Skip to main content
SpringerLink
Log in

Structuring oligodimethylsiloxanediols with trialkoxytitanium vanadates

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Kinetics of structuring oligodimethylsiloxanediols with trialkoxytitanium vanadates were studied. The apparent rate constants of structuring and the activation energies of the reactions were calculated. It was shown that during structuring the titanium and vanadium atoms embed into oligodimethylsiloxanediols to form polyelement organosiloxanes. The properties of the materials with coatings cured with trialkoxytitanium vanadates were investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Dolgov, O.N., Voronkov, M.G., and Grinblat, M.P., Kremniiorganicheskie zhidkie kauchuki i materialy na ikh osnove (Organosilicon Liquid Rubbers and Materials on Their Basis), Leningrad: Khimiya, 1975, p. 24.

    Google Scholar 

  2. Timofeeva, S.V., Osipov, A.E., and Khelevina, O.G., Pozharovzryvobezopasnost’, 2009, vol. 18, no. 5, p. 25.

    Google Scholar 

  3. Khelevina, O.G., RF Patent no. 2490288, Byull. Izobret., 2013, no. 23.

    Google Scholar 

  4. Khelevina, O.G., Russ. J. Appl. Chem., 2012, vol. 85, no. 2, p. 277. doi 10.1134/S1070427212020218

    Article  CAS  Google Scholar 

  5. Andrianov, K.A., Metody elementoorganicheskoi khimii (Methods of Organoelement Chemistry), Moscow: Nauka, 1968, p. 615.

    Google Scholar 

  6. Andrianov, K.A., Gribunov, I.T., and Khananashvili, L.M., Kauchuk Rezina, 1968, no. 11, p. 19–21.

    Google Scholar 

  7. Gruber, V.N., Klebanskii, A.L., Degteva, T.G., Kuzminskii, A.S., Mikhailova, T.A., and Kuzmina, E.V., Vysokomol. Soedin., 1965, vol. 7, no. 3, p. 462.

    CAS  Google Scholar 

  8. Khelevina, O.G., Russ. J. Appl. Chem., 2012, vol. 85, no. 7, p. 1142. doi 10.1134/S1070427212070270

    Article  CAS  Google Scholar 

  9. Feld, R. and Cowe, P.L., The Organic Chemistry of Titanium, London: Butterworths, 1965.

    Google Scholar 

  10. Dechant, J., Danz, R., Kimmer, W., and Schmolke, R., Ultrarotspektroskopische Untersuchungen an Polymeren, Berlin: Akademie, 1972.

    Google Scholar 

  11. Andrianov, K.A., Kurasheva, N.A., Lavrukhin, V.D., and Kuteinikova, L.I., Vysokomol. Soedin. A, 1972, vol. 14, no. 11, p. 2450.

    CAS  Google Scholar 

  12. Andrianov, K.A., Zhdanov, A.A., and Kashutina, E.Ya., Dokl. Akad. Nauk SSSR, 1959, vol. 126, no. 4, p. 1261.

    CAS  Google Scholar 

  13. Borisov, S.N., Voronkov, M.G., and Lukevits, E.Ya., Kremneelementoorganicheskie soedineniya (Silicon Element Compounds), Leningrad: Khimiya. 1966.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    O. G. Khelevina & A. S. Malyasova

Authors
  1. O. G. Khelevina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Malyasova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. G. Khelevina.

Additional information

Original Russian Text © O.G. Khelevina, A.S. Malyasova, 2015, published in Rossiiskii Khimicheskii Zhurnal, 2015, Vol. 59, No. 4, pp. 108–113.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khelevina, O.G., Malyasova, A.S. Structuring oligodimethylsiloxanediols with trialkoxytitanium vanadates. Russ J Gen Chem 87, 2233–2237 (2017). https://doi.org/10.1134/S1070363217090511

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363217090511

Keywords

Search

Navigation