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Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XV. Synthesis of bis-4,5-(phenylsulfanyl)phthalonitrile, octakis-4,5-(phenylsulfanyl)phthalocyanines, and their sulfo and alkylsulfamoyl derivatives

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Abstract

Novel water- and organic-soluble derivatives of octakis-4,5-(sulfanylphenyl)phthalocyanine and its magnesium and aluminum complexes were synthesized starting from 4,5-bis(phenylsulfanyl)phthalonitrile obtained by nucleophilic substitution of the bromine and nitro group in 4-bromo-5-nitrophthalonitrile. Spectral and luminescence characteristics of the newly synthesized compounds were studied.

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Authors and Affiliations

  1. Research Institute of Macroheterocyclic Chemistry, Ivanovo State University of Chemical Technology, pr. Sheteremetevskii 7, Ivanovo, 153000, Russia

    S. A. Znoiko, E. S. Golovashova, O. V. Potekhina, D. B. Berezin, M. A. Serova, V. E. Maizlish & G. P. Shaposhnikov

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  1. S. A. Znoiko
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  2. E. S. Golovashova
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  3. O. V. Potekhina
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  4. D. B. Berezin
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  5. M. A. Serova
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  6. V. E. Maizlish
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  7. G. P. Shaposhnikov
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Corresponding author

Correspondence to S. A. Znoiko.

Additional information

Original Russian Text © S.А. Znoiko, E.S. Golovashova, O.V. Potekhina, D.B. Berezin, M.А. Serova, V.E. Maizlish, G.P. Shaposhnikov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 7, pp. 1169–1178.

For communication XIV, see [1].

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Znoiko, S.A., Golovashova, E.S., Potekhina, O.V. et al. Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XV. Synthesis of bis-4,5-(phenylsulfanyl)phthalonitrile, octakis-4,5-(phenylsulfanyl)phthalocyanines, and their sulfo and alkylsulfamoyl derivatives. Russ J Gen Chem 87, 1562–1571 (2017). https://doi.org/10.1134/S1070363217070209

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