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Azobenzene palladium(II) complexes with β-diketones

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Abstract

A procedure has been developed for the synthesis of cyclometalated azobenzene palladium(II) complexes [Pd(O^O)Azb], where Azb– is deprotonated azobenzene and (O^O)– is deprotonated β-diketone (acetylacetone, thenoyltrifluoroacetone, benzoylacetone, or dibenzoylmethane). Electronic absorption spectra and electrochemical behavior of the synthesized complexes have been studied. It has been found that the lowest unoccupied molecular orbital of the complexes is contributed most by the π* orbital of azobenzene, and the highest occupied molecular orbital, by the palladium d orbital.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    M. V. Nikolaeva, E. K. Bogdanova & M. V. Puzyk

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  1. M. V. Nikolaeva
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  2. E. K. Bogdanova
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  3. M. V. Puzyk
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Correspondence to M. V. Nikolaeva.

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Original Russian Text © M.V. Nikolaeva, E.K. Bogdanova, M.V. Puzyk, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 3, pp. 481–484.

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Nikolaeva, M.V., Bogdanova, E.K. & Puzyk, M.V. Azobenzene palladium(II) complexes with β-diketones. Russ J Gen Chem 87, 485–488 (2017). https://doi.org/10.1134/S1070363217030185

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