Skip to main content
SpringerLink
Log in

Synthesis and spectroscopic studies of the new Ag(I) organoselenium complex

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The new complex of Ag(I) with an organoselenium compound was synthesized. The 2 : 1 (silver : ligand) stoichiometry of the complex and chelating mode of the hetero-selenium ligand have been considered on the basis of elemental analyses, IR, Raman, 1H and 13C NMR, and thermogravimetric data. The IR spectrum of the complex supported two sites of coordination (selenium and nitrogen atoms of quinoline moiety). The bidentate ligand was bound to selenium via oxygen atoms of the carboxylate group. The complex demonstrated the non-electrolyte nature. Nano-scale range of Ag(I) complex has been estimated according to X-ray powder diffraction, scanning electron microscope and transmission electron microscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Reily, C., in Selenium in Food and Health, London: Blackie Academic and Professional, 1997, p. 22, 1 ed.

    Google Scholar 

  2. Ihnat, M., in Occurrence and Distribution and Selenium, CRC Press, 2000, p. 286.

    Google Scholar 

  3. Craig, P.J., in Organometallic Compounds in the Environment, New York: Wiley, 2003, p. 391, 2 ed.

    Book  Google Scholar 

  4. Hancock, R.D., Nakani, B.S., and Marsicano, F., Inorg. Chem., 1983, vol. 22, p. 2531. DOI: 10.1021/ic00160a014.

    Article  CAS  Google Scholar 

  5. Cotton, F.A. and Wilkinson, G., Advanced Inorganic Chemistry: New York: Wiley, 1988, 5 ed.

    Google Scholar 

  6. Young, A.G. and Hanton, L.R., Coord. Chem. Rev., 2008, vol. 252, p. 1346. DOI: 10.1016/jccr.2007.07.017.

    Article  CAS  Google Scholar 

  7. Effendy F., Marchetti, F., Pettinarl, C., Pettinarl, R., Pizzablocca, A., Skelton, B.W., and White, A.H., Inorg. Chim. Acta, 2006, vol. 359, p. 1504. DOI: 10.1016/jccr.2007.07.017.

    Article  CAS  Google Scholar 

  8. Mehrotra, R.C., Metal Carboxylates, London Academic Press Inc., 1983.

    Google Scholar 

  9. Abdel-Hafez, Sh.H., Break, L.M., and Alsaadi, A.M., Phosphorus, Sulfur, and Silicon, 2013, vol. 188, p. 1281. DOI: 10.1080/10426507.2012.717138.

    Article  CAS  Google Scholar 

  10. Bauer, A.W., Kirby, W.M., Sherris, C., and Turck, M., Am. J. Clin. Pathol., 1966, vol. 45, p. 493. PubMed ID: 5325707.

    CAS  Google Scholar 

  11. Refat, M.S., Spectrochim. Acta A, 2007, vol. 68, p. 1393. DOI: 10.1016/jsaa.2006.12.078.

    Article  Google Scholar 

  12. Shanker, K., Rohini, R., Ravinder, V., Reddy, P.M., and Ho, Y.-P., Spectrochim. Acta A, 2009, vol. 73, p. 205. DOI: 10.1016/jsaa.2009.01.021.

    Article  Google Scholar 

  13. Deacon, G.B. and Phillips, R.J., Coord. Chem. Rev., 1980, vol. 33, p. 227. DOI: 10.1016/S0010-8545(00)80455-5.

    Article  CAS  Google Scholar 

  14. Chandra, S. and Sangeetika, X., Spectrochim. Acta A, 2004, vol. 60, p. 147. DOI: 10.1016/S1386-1425(03) 00220-8.

    Article  Google Scholar 

  15. Shakir, M., Chishti, H.-T.-N., and Chingsubam, P., Spectrochim. Acta A, 2006, vol. 64, p. 512. DOI: 10.1016/jsaa.2005.07.050.

    Article  Google Scholar 

  16. Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1970, 2 ed.

    Google Scholar 

  17. Devillanova, F.A., Diaz, A., Isaia, F., and Verani, G., Trans. Met. Chem., 1989, vol. 14, p. 153. DOI: 10.1007/BF01040612.

    Article  CAS  Google Scholar 

  18. Langevin, M.-A., Lachance-Quirion, D., Ritcey, A.M., and Allen, C.N., J. Phys. Chem. C, 2013, vol. 117, p. 5424. DOI: 10.1021/jp311206e.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Taif University, P.O. Box 888, Al-Hawiah, Taif, 21974, Saudi Arabia

    M. S. Refat & S. H. Abdel-Hafez

  2. Chemistry Department, Faculty of Science, Port Said University, Port Said, Egypt

    M. S. Refat

  3. Chemistry Department, Faculty of Science, Assiut University, Assiut, 71516, Egypt

    S. H. Abdel-Hafez

Authors
  1. M. S. Refat
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. H. Abdel-Hafez
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. S. Refat.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Refat, M.S., Abdel-Hafez, S.H. Synthesis and spectroscopic studies of the new Ag(I) organoselenium complex. Russ J Gen Chem 86, 1151–1153 (2016). https://doi.org/10.1134/S1070363216050285

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363216050285

Keywords

Search

Navigation