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Iridium-catalyzed cascade dehydrogenation, ring-closure reaction leading to 2,4,6-triaryl-1,3,5-triazines

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Abstract

An efficient iridium-catalyzed dehydrogenation, ring-closure reaction, has been developed via a cascade sequence, in which [Cp*IrI2]2/Xantphos proved to be the most efficient catalyst for the synthesis of 2,4,6-triaryl-1,3,5-triazines from stable aryl-substituted alcohols and amidines. It was the first case of iridium catalyst successful application in such transformation.

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Authors and Affiliations

  1. The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu Province, 214122, China

    Gang Shi, Fei He, Youxin Che, Caihua Ni & Ying Li

  2. National Engineering Laboratory for Cereal Fermentation Technology, Jiangnan University, Wuxi, Jiangsu Province, 214122, China

    Ying Li

Authors
  1. Gang Shi
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  2. Fei He
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  3. Youxin Che
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  4. Caihua Ni
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  5. Ying Li
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Corresponding author

Correspondence to Ying Li.

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The text was submitted by the authors in English.

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Shi, G., He, F., Che, Y. et al. Iridium-catalyzed cascade dehydrogenation, ring-closure reaction leading to 2,4,6-triaryl-1,3,5-triazines. Russ J Gen Chem 86, 380–386 (2016). https://doi.org/10.1134/S1070363216020304

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  • DOI: https://doi.org/10.1134/S1070363216020304

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