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State of atoms and interatomic interactions in perovskite-like oxides: XXXIV. State of europium atoms and exchange interactions in La1–y Eu y AlO3

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Abstract

A series of solid solutions of the La1–y Eu y AlO3 composition was studied by the method of magnetic dilution in the concentration range 1–20 mol % of europium atoms. Europium atoms in the solid solutions were found to take part in the antiferromagnetic superexchange interactions. Magnetic characteristics at the infinite dilution are described as existence of single Eu(III) atoms with a large contribution of Van Vleck’s temperature independent paramagnetism (∼0.001 emu/mol).

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References

  1. Chezhina, N.V and Fedorova, A.V., Russ. J. Gen. Chem., 2014, vol. 84, no. 12, p. 2382. DOI: 10.1134/S1070363214120044

    Article  CAS  Google Scholar 

  2. Kurbakov, A.I., Martin, C., and Maignan, A., J. Magn. Magn. Mater., 2009, vol. 321, no. 17, p. 2601. DOI: 10.1016/jjmmm. 2009.03.040.

    Article  CAS  Google Scholar 

  3. Boujelben, W., Cheikh-Rouhou, A., Pierre, J., Abou-Ras, D., Renard, J.P., and Shimizu, K., Physica (B), 2002, vol. 321, nos. 1–4, p. 68.

    Article  CAS  Google Scholar 

  4. Shao-Peng Liu, Yan Xie, Gui-De Tang, Zhuang-zhi Li, Deng-hui Ji, Yan-Feng Li, and Deng-Lu Hou, J. Magn. Magn. Mater., 2012, vol. 324, no. 12, p. 1992. DOI: 10.1016/jceramint. 2010.07.025.

    Article  CAS  Google Scholar 

  5. Ju-Hyeon, Lee, Jae-Chun, Lee, Myung-Kyun Park, and Sung Park, J. Mater. Proc. Technol., 2006, vol. 171, no. 2, p. 240. DOI: 10.1016/jjmatprotec.2005.06.069.

    Article  Google Scholar 

  6. Cheng, Z.X., Zhen, H.F., Li, A.H., Wang, X.L., and Kimura, H., J. Crystal Growth, 2005, vol. 275, nos. 1–2, p. e2415. DOI: 10.1016/jjcrysgro.2004.11.351.

    Article  CAS  Google Scholar 

  7. Sikora, M., Kapusta, Cz., Zajac, D., Tokarz, W., Oates, C.J., Borowiec, M., Rybicki, D., Goering, E., Fischer, P., Schutz, G., DeTeres, J.M., and Ibarra, M.R., J. Magn. Magn. Mater., 2004, vols. 272–276, p. 2148. DOI: 10.1016/jjmmm. 2003.12.659.

    Article  Google Scholar 

  8. Jia-qi Zhang, Na Lia, Ming Fenga, Bei-cheng Pana, and Hai-bo Lia, J. Alloys Compd., 2009, p. 88. DOI: 10.1016/jjallcom. 2007.12.045.

    Google Scholar 

  9. Dabrowski, B., Kolesnik, S., Baszczuk, A., Chmaissem, O., Maxwell, T., and Mais, J., J. Solid State Chem., 2005, vol. 178, no. 3, p. 629. DOI: 10.1016/jjssc.2004.12.006.

    Article  CAS  Google Scholar 

  10. Sharov, V.A., Bazuev, G.V., Zuev, M.G., and Bamburov, V.G., Kompleksy oksalatov 3d- i 4d-elementov s gidrazinom (Complexes of 3d- and 4delements with Hydrazine), Yekaterinburg: Ural. Otd. Ross. Akad. Nauk, 2004.

    Google Scholar 

  11. Kalinnikov, V.T. and Rakitin, Yu.A., Sovremennaya magnetokhimiya (Modern Magnetochemistry), St. Petersburg: Nauka, 1984.

    Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    A. V. Fedorova, N. V. Chezhina & V. V. Shilovskikh

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  1. A. V. Fedorova
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  2. N. V. Chezhina
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  3. V. V. Shilovskikh
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Correspondence to A. V. Fedorova.

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Original Russian Text © A.V. Fedorova, N.V. Chezhina, V.V. Shilovskikh, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 10, pp. 1589–1593.

For communication XXXIII, see [1].

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Fedorova, A.V., Chezhina, N.V. & Shilovskikh, V.V. State of atoms and interatomic interactions in perovskite-like oxides: XXXIV. State of europium atoms and exchange interactions in La1–y Eu y AlO3 . Russ J Gen Chem 85, 2223–2226 (2015). https://doi.org/10.1134/S1070363215100011

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  • DOI: https://doi.org/10.1134/S1070363215100011

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