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Alcohol associates as catalysts of tautomeric transformations

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Abstract

The B3LYP/6-311++G(df,p) quantum-chemical simulation has revealed that linear associates of methanol catalyze the ketone–enol, nitro–aci-nitro, and carbamate–azomethinenol tautomeric transformations. All the reactions proceed via the coherent transition states. The catalytic effect is enhanced with the increased alcohol degree of association. The acid-base properties of methanol are changed similarly.

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Authors and Affiliations

  1. Kazan National Research Technological University, ul. K. Marksa 68, Kazan, Tatarstan, 420015, Russia

    A. Ya. Samuilov, F. B. Balabanova & Ya. D. Samuilov

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan National Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    A. I. Konovalov

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  1. A. Ya. Samuilov
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  2. F. B. Balabanova
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  3. Ya. D. Samuilov
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  4. A. I. Konovalov
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Correspondence to Ya. D. Samuilov.

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Original Russian Text © A.Ya. Samuilov, F.B. Balabanova, Ya.D. Samuilov, A.I. Konovalov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 8, pp. 1249–1256.

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Samuilov, A.Y., Balabanova, F.B., Samuilov, Y.D. et al. Alcohol associates as catalysts of tautomeric transformations. Russ J Gen Chem 85, 1808–1815 (2015). https://doi.org/10.1134/S1070363215080034

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