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Substituent effect on the rate of thermal decomposition of 5-(R-phenyl)-2-methyl-1,2,3,4-tetrazoles

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Abstract

Thermal decomposition of substituted 2-methyl-5-phenyltetrazoles in solution has been studied by manometric method with chromatographic determination of the evolved nitrogen. A relation has been found between the rate of thermal decomposition and nature of the substituent in the benzene ring. Effects of solvent and temperature on thermal decomposition of substituted tetrazoles have been revealed.

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Authors and Affiliations

  1. Siberian State Technological University, pr. Mira 82, Krasnoyarsk, 660049, Russia

    R. S. Stepanov & L. A. Kruglyakova

Authors
  1. R. S. Stepanov
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  2. L. A. Kruglyakova
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Correspondence to L. A. Kruglyakova.

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Original Russian Text © R.S. Stepanov, L.A. Kruglyakova, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 5, pp. 741–744.

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Stepanov, R.S., Kruglyakova, L.A. Substituent effect on the rate of thermal decomposition of 5-(R-phenyl)-2-methyl-1,2,3,4-tetrazoles. Russ J Gen Chem 85, 1040–1042 (2015). https://doi.org/10.1134/S1070363215050059

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  • DOI: https://doi.org/10.1134/S1070363215050059

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