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Colloid and nanosized catalysts in organic synthesis: V. Reactions of alkyl halides and alcohols with β-diketones in the presence of metal nanoparticles

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Abstract

Reaction of copper, nickel, and iron nanoparticles with β-diketones directly yields corresponding metal β-diketonates. Reaction of alkyl halides, β-diketones, and nanodispersed metals leads to a mixture of monoketone and the alkylated β-diketone. When alcohol is used as the alkylating agent instead of alkyl halide, corresponding ester is formed.

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Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia

    Yu. V. Popov & V. M. Mokhov

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  1. Yu. V. Popov
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  2. V. M. Mokhov
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Correspondence to Yu. V. Popov.

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Original Russian Text © Yu.V. Popov, V.M. Mokhov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 8, pp. 1263–1267.

For communication IV, see [1].

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Popov, Y.V., Mokhov, V.M. Colloid and nanosized catalysts in organic synthesis: V. Reactions of alkyl halides and alcohols with β-diketones in the presence of metal nanoparticles. Russ J Gen Chem 84, 1491–1495 (2014). https://doi.org/10.1134/S1070363214080076

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  • DOI: https://doi.org/10.1134/S1070363214080076

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