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Ligand Metathesis in Nickel(II) Complexation with closo-Decaborate Anion

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Abstract

Nickel(II) complexation with the closo-decaborate anion in water and acetonitrile is studied. Complexes [Ni(solv)6][B10H10] (solv = H2O (I) or CH3CN (II)) are isolated. The complexes are characterized by elemental analysis and IR spectroscopy. Complex [Ni(CH3CN)5(H2O)]0.75[Ni(CH3CN)4(H2O)2]0.25[B10H10]·0.5H2O (III) is isolated from an acetonitrile–water system. The structure of complex III is solved by X-ray diffraction (XRD) (CIF file CCDС no. 2224702). A mechanism of ligand metathesis in the complexation of nickel(II) is proposed.

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Funding

The work was carried out in terms of State assignment of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the field of fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. V. Avdeeva, A. S. Kubasov, S. E. Nikiforova, L. V. Goeva, E. A. Malinina & N. T. Kuznetsov

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  1. V. V. Avdeeva
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  2. A. S. Kubasov
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  3. S. E. Nikiforova
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  4. L. V. Goeva
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Correspondence to V. V. Avdeeva.

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Translated by E. Yablonskaya

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This article is prepared for the memorial issue in tribute to the Corresponding Member of the Russian Academy of Sciences K.Yu. Zhizhin on his 50th birthday.

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Avdeeva, V.V., Kubasov, A.S., Nikiforova, S.E. et al. Ligand Metathesis in Nickel(II) Complexation with closo-Decaborate Anion. Russ J Coord Chem 49, 338–344 (2023). https://doi.org/10.1134/S1070328423600171

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