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Synthesis and Structures of Tris(3-fluorophenyl)antimony Dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = СH2С6H4F-3, С6H3F2-2,3, and С6F5)

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Abstract

Tris(3-fluorophenyl)antimony dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = СH2С6H4F-3 (I), С6H3F2-2,3 (II), and С6F5 (III)) are synthesized via oxidative addition from tris(3-fluorophenyl)antimony, carboxylic acid, and tert-butyl hydroperoxide in a diethyl ether solution. The structures of the compounds are characterized by IR spectroscopy, 1Н, 13С{1Н}, and 19F{1Н} NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction (CIF files CCDC nos. 2055807 (I), 2055816 (II), and 2055817 (III)). The crystals of complexes I−III contain the trigonal bipyramidal molecules with the axially arranged carboxylate ligands.

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Authors and Affiliations

  1. South Ural State University (National Research University), Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & D. A. Zherebtsov

  2. Ural Federal University, Yekaterinburg, Russia

    O. S. El’tsov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. D. A. Zherebtsov
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  4. O. S. El’tsov
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Correspondence to V. V. Sharutin.

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Translated by E. Yablonskaya

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Sharutin, V.V., Sharutina, O.K., Zherebtsov, D.A. et al. Synthesis and Structures of Tris(3-fluorophenyl)antimony Dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = СH2С6H4F-3, С6H3F2-2,3, and С6F5). Russ J Coord Chem 48, 218–223 (2022). https://doi.org/10.1134/S1070328422040030

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