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Synthesis and Crystal Structures of the Reaction Products of the Magnesium Acenaphthenediimine Complex with Tosyl Azide

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Abstract

The reaction of [(Dpp-Bian)Mg(THF)3] (I) (Dpp-Bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with tosyl azide (TosN3) affords the binuclear amide complex [(Dpp-Bian)Mg(THF)(NTos)(THF)Mg(Dpp-Bian)] (II) in which the magnesium atoms are linked with the nitrogen atom by the bridging p-tolylsulfamide group. In the presence of pyridine, the reaction leads to the compound [(Dpp-Bian)Mg(Py)(NTos)(Py)Mg(Dpp-Bian)] (III) in which NTos has different coordination modes with the metal atoms. The diimine ligand is in the radical anion state in both compounds. New paramagnetic compounds II and III are characterized by IR spectroscopy, EPR spectroscopy, elemental analysis, and X-ray diffraction analysis (СFА files CCDC no. 1878433 (II · 1.5C5H12) and 1878432 (III · 2C7H8 · 0.5OC4H8)).

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REFERENCES

  1. Fedushkin, I.L., Skatova, A.A., Chudakova, V.A., et al., Eur. J. Inorg. Chem., 2003, vol. 2003, no. 18, p. 3336.

    Article  CAS  Google Scholar 

  2. Fedushkin, I.L., Chudakova, V.A., Skatova, A.A., et al., Z. Anorg. Allg. Chem., 2004, vol. 630, no. 4, p. 501.

    Article  CAS  Google Scholar 

  3. Fedushkin, I.L., Chudakova, V.A., Skatova, A.A., and Fukin, G.K., Heteroatom Chem., 2005, vol. 16, no. 7, p. 663.

    Article  CAS  Google Scholar 

  4. Fedushkin, I.L., Skatova, A.A., Cherkasov, V.K., et al., Chem.-Eur. J., 2003, vol. 9, no. 23, p. 5778.

    Article  CAS  PubMed  Google Scholar 

  5. Fedushkin, I.L., Khvoinova, N.M., Skatova, A.A., and Fukin, G.K., Angew. Chem., Int. Ed. Engl., 2003, vol. 42, no. 42, p. 5223.

    Article  CAS  Google Scholar 

  6. Fedushkin, I.L., Skatova, A.A., Lukoyanov, A.N., et al., Russ. Chem. Bull., 2004, vol. 53, no. 12, p. 2751.

    Article  CAS  Google Scholar 

  7. Fedushkin, I.L., Skatova, A.A., Fukin, G.K., et al., Eur. J. Inorg. Chem., 2005, vol. 2005, no. 12, p. 2332.

    Article  CAS  Google Scholar 

  8. Fedushkin, I.L., Chudakova, V.A., and Hummert, M., Schumann, H., Z. Naturforsch., B: Chem. Sci., 2008, vol. 63, no. 2, p. 161.

    CAS  Google Scholar 

  9. Fedushkin, I.L., Makarov, V.M., Rosenthal, E.C.E., and Fukin, G.K., Eur. J. Inorg. Chem., 2006, vol. 2006, no. 4, p. 827.

    Article  CAS  Google Scholar 

  10. Bourget-Merle, L., Lappert, M.F., and Severn, J.R., Chem. Rev., 2002, vol. 102, no. 9, p. 3031.

    Article  CAS  PubMed  Google Scholar 

  11. Tsai, Y.-C., Coord. Chem. Rev., 2012, vol. 256, no. 5, p. 722.

    Article  CAS  Google Scholar 

  12. Green, S.P., Jones, C., and Stasch, A., Science, 2007, vol. 318, no. 5857, p. 1754.

    Article  CAS  PubMed  Google Scholar 

  13. Stasch, A. and Jones, C., Dalton Trans., 2011, vol. 40, no. 21, p. 5659.

    Article  CAS  PubMed  Google Scholar 

  14. Bonyhady, S.J., Jones, C., Nembenna, S., et al., Chem.-Eur. J., 2010, vol. 16, no. 3, p. 938.

    Article  CAS  PubMed  Google Scholar 

  15. Jones, C., Nature Rev. Chem., 2017, vol. 1, p. 0059.

  16. Bonyhady, S.J., Green, S.P., Jones, C., et al., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, no. 16, p. 2973.

    Article  CAS  Google Scholar 

  17. Jones, C., McDyre, L., Murphy, D.M., and Stasch, A., Chem. Commun., 2010, vol. 46, no. 9, p. 1511.

    Article  CAS  Google Scholar 

  18. Lalrempuia, R., Stasch, A., and Jones, C., Chem. Sci., 2013, vol. 4, no. 12, p. 4383.

    Article  CAS  Google Scholar 

  19. Boutland, A.J., Pernik, I., Stasch, A., and Jones, C., Chem.-Eur. J., 2015, vol. 21, no. 44, p. 15749.

    Article  CAS  PubMed  Google Scholar 

  20. Anker, M.D., Kefalidis, C.E., Yang, Y., et al., J. Am. Chem. Soc., 2017, vol. 139, no. 29, p. 10036.

    Article  CAS  PubMed  Google Scholar 

  21. Fedushkin, I.L., Lukoyanov, A.N., Ketkov, S.Y., et al., Chem.-Eur. J., 2007, vol. 13, no. 25, p. 7050.

    Article  CAS  PubMed  Google Scholar 

  22. Fedushkin, I.L., Lukoyanov, A.N., Fukin, G.K., et al., Chem.-Eur. J., 2008, vol. 14, no. 28, p. 8465.

    Article  CAS  PubMed  Google Scholar 

  23. Fedushkin, I.L., Lukoyanov, A.N., Tishkina, A.N., et al., Chem.-Eur. J., 2010, vol. 16, no. 25, p. 7563.

    Article  CAS  PubMed  Google Scholar 

  24. Sanden, T., Gamer, M.T., Fagin, A.A., et al., Organometallics, 2012, vol. 31, no. 11, p. 4331.

    Article  CAS  Google Scholar 

  25. Fedushkin, I.L., Dodonov, V.A., Skatova, A.A., et al., Chem.-Eur. J., 2018, vol. 24, no. 8, p. 1877.

    Article  CAS  PubMed  Google Scholar 

  26. Fedushkin, I.L., Skatova, A.A., Dodonov, V.A., et al., Inorg. Chem., 2014, vol. 53, no. 10, p. 5159.

    Article  CAS  PubMed  Google Scholar 

  27. Fedushkin, I.L., Nikipelov, A.S., Morozov, A.G., et al., Chem.-Eur. J., 2012, vol. 18, no. 1, p. 255.

    Article  CAS  PubMed  Google Scholar 

  28. Fedushkin, I.L., Nikipelov, A.S., and Lyssenko, K.A., J. Am. Chem. Soc., 2010, vol. 132, no. 23, p. 7874.

    Article  CAS  PubMed  Google Scholar 

  29. Zhang, W., Dodonov, V.A., Chen, W., et al., Chem.-Eur. J., 2018, vol. 24, no. 56, p. 14994.

    Article  CAS  PubMed  Google Scholar 

  30. Fedushkin, I.L., Skatova, A.A., Dodonov, V.A., et al., Inorg. Chem., 2016, vol. 55, no. 17, p. 9047.

    Article  CAS  PubMed  Google Scholar 

  31. Dodonov, V.A., Skatova, A.A., Cherkasov, A.V., and Fedushkin, I.L., Russ. Chem. Bull., 2016, vol. 65, no. 5, p. 1171.

    Article  CAS  Google Scholar 

  32. Paulovicova, A., El-Ayaan, U., Shibayama, K., et al., Eur. J. Inorg. Chem., 2001, vol. 2001, no. 10, p. 2641.

    Article  Google Scholar 

  33. Curphey, T.J., Org. Prep. Proc. Int., 2009, vol. 13, no. 2, p. 112.

    Article  Google Scholar 

  34. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  35. Peng, Y.-L., Huang, Y., Chuang, H.-J., et al., Polymer, 2010, vol. 51, no. 19, p. 4329.

    Article  CAS  Google Scholar 

  36. Blake, M.P., Schwarz, A.D., and Mountford, P., Organometallics, 2011, vol. 30, no. 5, p. 1202.

    Article  CAS  Google Scholar 

  37. Zhao, J., Song, H., and Cui, C., Organometallics, 2007, vol. 26, no. 8, p. 1947.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The work on the synthesis and X-ray diffraction studies of the compounds obtained was carried out with the financial support of the Russian Science Foundation (project 14-13-01063), the EPR spectroscopic characterization of metal complexes was supported by the Russian Fund for Basic Research (project 18-33-01057).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603600, Nizhny Novgorod, Russia

    V. A. Dodonov, A. A. Skatova & I. L. Fedushkin

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  1. V. A. Dodonov
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  2. A. A. Skatova
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  3. I. L. Fedushkin
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Correspondence to I. L. Fedushkin.

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Dedicated to the 90th birthday of Academician I.I. Moiseev

Translated by E. Yablonskaya

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Dodonov, V.A., Skatova, A.A. & Fedushkin, I.L. Synthesis and Crystal Structures of the Reaction Products of the Magnesium Acenaphthenediimine Complex with Tosyl Azide. Russ J Coord Chem 45, 301–307 (2019). https://doi.org/10.1134/S1070328419040031

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  • DOI: https://doi.org/10.1134/S1070328419040031

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