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Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines

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Abstract

The complexes [Zn(CH3COO)2(NioxH2)(DMF)(H2O)] (I), [Cd(CH3COO)2-(NioxH2)(DMF)(H2O)] (II), [Zn(CH3COO)2(NioxH2)(S-Nia)(H2O)] · DMF (III), [Zn(CH3COO)2(NioxH2)(Nia)(H2O)] (IV), and [Zn(CH3COO)2(NioxH2)(INia)(H2O)] (V), where NioxH2 is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is iso-nicotinamide, were prepared and investigated. Compounds I–III were studied by X-ray diffraction (CCDC nos. 1505280–1505282 for I–III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of Moldova, Chisinau, Moldova

    E. Coropceanu

  2. Tiraspol State University, Chisinau, Moldova

    E. Coropceanu & S. Codreanu

  3. Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Moldova

    L. Croitor & M. Fonari

  4. Institute of Microbiology and Biotechnology, Academy of Sciences of Moldova, Chisinau, Moldova

    A. Ciloci, S. Clapco & S. Labliuc

Authors
  1. E. Coropceanu
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  2. L. Croitor
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  3. A. Ciloci
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  4. S. Clapco
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  5. S. Labliuc
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  6. S. Codreanu
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  7. M. Fonari
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Correspondence to E. Coropceanu.

Additional information

Original Russian Text © E. Coropceanu, L. Croitor, A. Ciloci, S. Clapco, S. Labliuc, S. Codreanu, M. Fonari, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 7, pp. 399–406.

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Coropceanu, E., Croitor, L., Ciloci, A. et al. Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines. Russ J Coord Chem 43, 433–440 (2017). https://doi.org/10.1134/S1070328417070053

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  • DOI: https://doi.org/10.1134/S1070328417070053

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