Skip to main content
SpringerLink
Log in

Synthesis, crystal structures, and catalytic property of dioxomolybdenum(VI) complexes with hydrazone ligands derived from 3,5-Di-tert-butylsalicylaldehyde

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Two new dioxomolybdenum(VI) complexes, [MoO2L1(MeOH)] (I) and [MoO2L2] (II), where L1 and L2 are the anionic forms of N'-(2-hydroxy-3,5-di-tert-butylbenzylidene)-4-methoxybenzohydrazide and 2-amino-N'-(2-hydroxy-3,5-di-tert-butylbenzylidene)benzohydrazide, respectively, have been synthesized and characterized by elemental analysis, FT-IR spectra, and single crystal X-ray determination (CF files CCDC nos. 1448089 (I), 1487063 (II)). The crystal of I is monoclinic: space group P21/n, a = 7.353(1), b = 24.758(3), c = 13.891(2) Å, β = 101.013(2)°, V = 2482.3(6) Å3, Z = 4, R 1 = 0.0848, wR 2 = 0.2050. The crystal of II is monoclinic: space group P21/c, a = 6.752(1), b = 16.947(1), c = 19.510(1) Å, β = 96.891(2)°, V = 2216.5(4) Å3, Z = 4, R 1 = 0.0670, wR 2 = 0.1638. The Mo atom in complex I is in octahedral coordination, with three donor atoms of the hydrazone ligand, two oxo groups, and one methanol O atom. The Mo atom in complex II is in square pyramidal coordination, with three donor atoms of the hydrazone ligand, and two oxo groups. The complexes have interesting catalytic properties for sulfoxidation reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Gamelas, C.A., Gomes, A.C., Bruno, S.M., et al., Dalton Trans., 2012, vol. 41, no. 10, p. 3474.

    Article  CAS  Google Scholar 

  2. Feng, L.S., Maass, J.S., and Luck, R.L., Inorg. Chim. Acta, 2011, vol. 373, p. 85.

    Article  CAS  Google Scholar 

  3. Bagherzadeh, M., Amini, M., Ellern, A., et al., Inorg. Chem. Commun., 2012, vol. 15, no. 1, p. 52.

    Article  CAS  Google Scholar 

  4. Rayati, S., Rafiee, N., and Wojtczak, A., Inorg. Chim. Acta, 2012, vol. 386, p. 27.

    Article  CAS  Google Scholar 

  5. Ceylan, B.I., Kurt, Y.D., and Ulkuseven, B., J. Coord. Chem., 2009, vol. 62, no. 5, p. 757.

    Article  CAS  Google Scholar 

  6. Sokolov, M.N., Mikhailov, M.A., Abramov, P.A., et al., J. Struct. Chem., 2012, vol. 53, no. 1, p. 197.

    Article  CAS  Google Scholar 

  7. Gao, S.-P., J. Coord. Chem., 2011, vol. 64, no. 16, p. 2869.

    Article  CAS  Google Scholar 

  8. Mandal, S., Saha, R., Mahanti, B., et al., Inorg. Chim. Acta, 2012, vol. 387, p. 1.

    Article  CAS  Google Scholar 

  9. Vazquez-Fernandez, M.A., Fernandez-Garcia, M.I., Gonzalez-Noya, A.M., et al., Polyhedron, 2012, vol. 31, no. 1, p. 379.

    Article  Google Scholar 

  10. Habib, F., Lin, P.-H., Long, J., et al., J. Am. Chem. Soc., 2011, vol. 133, no. 23, p. 8830.

    Article  CAS  Google Scholar 

  11. Rayati, S., Rafiee, N., and Wojtczak, A., Inorg. Chim. Acta, 2012, vol. 386, p. 27.

    Article  CAS  Google Scholar 

  12. Ngan, N.K., Lo, K.M., and Wong, C.S.R., Polyhedron, 2012, vol. 33, no. 1, p. 235.

    Article  CAS  Google Scholar 

  13. Duman, S., Kizilcikli, I., Koca, A., et al., Polyhedron, 2010, vol. 29, no. 15, p. 2924.

    Article  CAS  Google Scholar 

  14. Chakravarthy, R.D., Suresh, K., Ramkumar, V., et al., Inorg. Chim. Acta, 2011, vol. 376, p. 57.

    Article  CAS  Google Scholar 

  15. Rao, C.P., Sreedhara, A., Rao, P.V., et al., J. Chem. Soc., Dalton Trans., 1998, no. 14, p. 2383.

    Article  Google Scholar 

  16. Mancka, M. and Plass, W., Inorg. Chem. Commun., 2007, vol. 10, no. 6, p. 677.

    Article  CAS  Google Scholar 

  17. Rao, S.N., Kathale, N., Rao, N.N., et al., Inorg. Chim. Acta, 2007, vol. 360, no. 14, p. 4010.

    Article  CAS  Google Scholar 

  18. Dinda, R., Ghosh, S., Falvello, L.R., et al., Polyhedron, 2006, vol. 25, no. 12, p. 2375.

    Article  CAS  Google Scholar 

  19. Shi, L., Xiao, Z.-P., Zhuang, Z., et al., Acta Crystallogr., Sect, E: Struct. Rep. Online, 2007, vol. 63, no. 12, p. o4726.

    Article  CAS  Google Scholar 

  20. Xue, L.-W., Han, Y.-J., Zhao, G.-Q., et al., J. Chem. Crystallogr., 2011, vol. 41, no. 11, p. 1599.

    Article  CAS  Google Scholar 

  21. Bruker, SMART and SAINT. Area Detector Control and Integration Software, Madison: Bruker Analytical X-ray Instruments Inc., 1997.

  22. Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  23. North, A.C.T., Phillips, D.C., and Mathews, F.S., Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr., 1968, vol. 24, no. 3, p. 351.

    Article  Google Scholar 

  24. Sheldrick, G.M., SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  25. Rao, S.N., Munshi, K.N., Rao, N.N., et al., Polyhedron, 1999, vol. 18, no. 19, p. 2491.

    Article  CAS  Google Scholar 

  26. Xu, W.-X. and Li, W.-H., Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2012, vol. 42, no. 2, p. 160.

    Article  CAS  Google Scholar 

  27. Glowiak, T., Jerzykiewicz, L., Sobczak, J.A., et al., Inorg. Chim. Acta, 2003, vol. 356, p. 387.

    Article  CAS  Google Scholar 

  28. Romanowski, G. and Wera, M., Polyhedron, 2010, vol. 29, no. 13, p. 2747.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan Henan, 467000, P.R. China

    L. Wang, Y. J. Han, Q. B. Li & L. W. Xue

Authors
  1. L. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. J. Han
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Q. B. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. W. Xue
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. W. Xue.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, L., Han, Y.J., Li, Q.B. et al. Synthesis, crystal structures, and catalytic property of dioxomolybdenum(VI) complexes with hydrazone ligands derived from 3,5-Di-tert-butylsalicylaldehyde. Russ J Coord Chem 43, 389–395 (2017). https://doi.org/10.1134/S1070328417060094

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328417060094

Keywords

Search

Navigation