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Polymer chlorobismuthate complex catena-{((Me,Me)Bpe)[BiCl5]} n : Synthesis and crystal structure

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Abstract

The reaction of BiCl3 and N,N-dimethyl-1,2-bis(pyridyl)ethane chloride (Me,Me-Bpe) in 2 M HCl affords a polymer chlorobismuthate complex {((Me,Me)Bpe)[BiCl5]} n (I). The structure of complex I is determined by X-ray diffraction analysis (CIF file CCDC 1058842). The anionic moiety of the complex is presented by a 1D coordination polymer ([BiCl5]2n–) n consisting of octahedral blocks {Cl6} linked by µ2- bridging chloride ligands into infinite zigzag chains.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. A. Adonin, D. G. Samsonenko, M. N. Sokolov & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    S. A. Adonin, D. G. Samsonenko, M. N. Sokolov & V. P. Fedin

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  1. S. A. Adonin
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  2. D. G. Samsonenko
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  3. M. N. Sokolov
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  4. V. P. Fedin
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Correspondence to S. A. Adonin.

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Original Russian Text © S.A. Adonin, D.G. Samsonenko, M.N. Sokolov, V.P. Fedin, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 1, pp. 29–33.

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Adonin, S.A., Samsonenko, D.G., Sokolov, M.N. et al. Polymer chlorobismuthate complex catena-{((Me,Me)Bpe)[BiCl5]} n : Synthesis and crystal structure. Russ J Coord Chem 42, 27–31 (2016). https://doi.org/10.1134/S1070328416010012

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  • DOI: https://doi.org/10.1134/S1070328416010012

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