Skip to main content
SpringerLink
Log in

Syntheses, structures, magnetic properties, and photoluminescence of compounds Ln(2,2′-Bipy)(C4H8NCS2)3 · 0.5CH2Cl2 (Ln = Sm, Eu, Tb, Dy, and Tm)

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Five compounds of the composition Ln(2,2′-Bipy)(C4H8NCS2)3 · 0.5CH2Cl2 (Ln = Sm (I), Eu (II), Tb (III), Dy (IV), and Tm (V); 2,2′-Bipy = 2,2′-bipyridine) are synthesized. According to the X-ray diffraction data (CIF file CCDC 986259), the crystal structure of compound I consists of molecules of the mononuclear complex [Sm(2,2′-Bipy)(C4H8NCS2)3] and solvate molecules CH2Cl2 (2 : 1). The coordination polyhedron N2S6 of the Sm atom is a distorted tetragonal antiprism. The X-ray diffraction analysis shows that compounds I–V are isostructural. The magnetic properties of compounds I–V are analyzed in the temperature range from 2 to 300 K. At 300 K compounds I and III are photoluminescent in the visible spectral range. The photoluminescence intensity of compound I considerably exceeds that of complex III.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. De Sa, G.F., Malta, O.L., de Mello Donega, C., et al., Coord. Chem. Rev., 2000, vol. 196, no. 1, p. 165.

    Article  Google Scholar 

  2. Bunzli, J.-C.G., Acc. Chem. Res., 2006, vol. 39, no. 1, p. 53.

    Article  Google Scholar 

  3. Metelitsa, A.V., Burlov, A.S., Bezuglyi, S.O., et al., Rus. J. Coord. Chem., 2006, vol. 32, no. 12, p. 858.

    Article  CAS  Google Scholar 

  4. Armelao, L., Quici, S., Barigelletti, E., et al., Coord. Chem. Rev., 2010, vol. 254, nos 5–6, p. 487.

    Article  CAS  Google Scholar 

  5. Bochkarev, M.N., Vitukhnovskii, A.G., and Katkova, M.A., Organicheskie svetoizluchayushchie diody (OLED) (Organic Light-Emitting Diodes), Novgorod: Dekom, 2011.

    Google Scholar 

  6. Kumar, G.A., Riman, R.E., Diaz Torres, L.A., et al., Chem. Mater., 2005, vol. 17, no. 20, p. 5130.

    Article  CAS  Google Scholar 

  7. Banerjee, S., Huebner, L., Romanelli, M.D., et al., J. Am. Chem. Soc., 2005, vol. 127, no. 45, p. 15900.

    Article  CAS  Google Scholar 

  8. Katkova, M.A., Borisov, A.V., Fukin, G.K., et al., Inorg. Chim. Acta, 2006, vol. 359, no. 13, p. 4289.

    Article  CAS  Google Scholar 

  9. Katkova, M.A., Ilishev, V.A., Konev, A.N., et al., Organic Electronics, 2009, vol. 10, no. 4, p. 623.

    Article  CAS  Google Scholar 

  10. Kobayashi, T., Naruke, H., and Yamase, T., Chem. Lett., 1997, vol. 26, no. 9, p. 907.

    Article  Google Scholar 

  11. Su, C.G., Tan, M.Y., Tang, N., et al., J. Coord. Chem., 1996, vol. 38, no. 3, p. 207.

    Article  CAS  Google Scholar 

  12. Varand, V.L., Glinskaya, L.A., Klevtsova, R.F., and Larionov, S.V., Zh. Strukt. Khim., 1998, vol. 39, no. 2, p. 300.

    Google Scholar 

  13. Faustino, W.M., Malta, O.L., Teotonio, E.E.S., et al., J. Phys. Chem. A, 2006, vol. 110, no. 7, p. 2510.

    Article  CAS  Google Scholar 

  14. Regulacio, M.D., Publico, M.H., Vasquez, J.A., et al., Inorg. Chem., 2008, vol. 47, no. 5, p. 1512.

    Article  CAS  Google Scholar 

  15. Meng, X.-X., Gao, S.-L., Chen, S.-P., et al., Acta Chim. Sinica, 2004, vol. 62, no. 22, p. 2233.

    CAS  Google Scholar 

  16. Chen, S.P., Meng, X.X., Shuai, Q., et al., J. Therm. Anal. Cal., 2006, vol. 86, no. 3, p. 767.

    Article  CAS  Google Scholar 

  17. Chen, S.P., Gao, S.L., Yang, X.W., et al., Rus. J. Coord. Chem., 2007, vol. 33, no. 3.

    Google Scholar 

  18. Selinsky, R.S., Han, J.H., Morales Perez, E.A. et al., J. Am. Chem. Soc., 2010, vol. 132, no. 45, p. 15997.

    Article  CAS  Google Scholar 

  19. Bryleva, Yu.A., Glinskaya, L.A., Korol’kov, I.V., et al., J. Struct. Chem., 2014, vol. 55, no. 2, p. 319.

    Article  CAS  Google Scholar 

  20. Bryleva, Yu.A., Kokina, T.E., Uskov, E.M., et. al., Rus. J. Coord. Chem., 2013, vol. 39, no. 1, p. 41.

    Article  CAS  Google Scholar 

  21. Sheldrick G.M., SHELXS-97 and SHELXL-97. Programs for the Refinement of Crystal Struñtures, Gottingen (Germany): Univ. of Gottingen, 1997.

    Google Scholar 

  22. Varand, V.L., Glinskaya, L.A., Klevtsova, R.F., and Larionov, S.V., Zh. Strukt. Khim., 2000, vol. 41, no. 3, p. 663.

    Google Scholar 

  23. Kraus, W., Nolze, G., J. Appl. Cryst., 1996, vol. 29, no. 3, p. 301.

    Article  CAS  Google Scholar 

  24. Byr’ko, V.M., Ditiokarbamaty (Dithiocarbamates), Ìoscow: Nauka, 1984, p. 61.

    Google Scholar 

  25. Cotton, S. Lanthanide and Actinide Chemistry, Chichester: Wiley, 2006, p. 65.

    Book  Google Scholar 

  26. Andruh, M., Bakalbassis, E., Kahn, O., et al., Inorg. Chem., 1993, vol. 32, no. 9, p. 1616.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    Yu. A. Bryleva, L. A. Glinskaya, I. V. Korol’kov, M. I. Rakhmanova, D. Yu. Naumov, T. E. Kokina & S. V. Larionov

  2. Novosibirsk State University, Pirogova st. 2, Novosibirsk, 630090, Russia

    I. V. Korol’kov, T. E. Kokina & S. V. Larionov

  3. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. S. Bogomyakov

Authors
  1. Yu. A. Bryleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Glinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Korol’kov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Bogomyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. I. Rakhmanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. Yu. Naumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. T. E. Kokina
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. S. V. Larionov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. A. Bryleva.

Additional information

Original Russian Text © Yu.A. Bryleva, L.A. Glinskaya, I.V. Korol’kov, A.S. Bogomyakov, M.I. Rakhmanova, D.Yu. Naumov, T.E. Kokina, S.V. Larionov, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 10, pp. 623–630.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bryleva, Y.A., Glinskaya, L.A., Korol’kov, I.V. et al. Syntheses, structures, magnetic properties, and photoluminescence of compounds Ln(2,2′-Bipy)(C4H8NCS2)3 · 0.5CH2Cl2 (Ln = Sm, Eu, Tb, Dy, and Tm). Russ J Coord Chem 40, 740–747 (2014). https://doi.org/10.1134/S1070328414100029

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328414100029

Keywords

Search

Navigation