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Electrical and Mechanical Properties of CeO2-Based Thin-Film Coatings Obtained by Electrophoretic Deposition

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Abstract

Nanometer Ce0.8(Sm0.75Sr0.20Ba0.05)0.2O2 – δ powder with mean nanoparticle size of 15 nm has been obtained by laser evaporation of a solid-phase target followed by condensation. The nanopowder has been used to prepare suspensions for electrophoretic deposition in a mixed isopropanol : acetyl acetone = 50 : 50 vol % disperse medium offering the unique property of self-stabilization. Optimal conditions for electrophoretic deposition have been found, and uniform thin-film electrolytic coatings have been formed on a La2NiO4 cathodic carrier substrate (12–15% porosity). It has been shown that the resulting electrolyte offers a high adhesivity and has, after sintering at 1400°C, a compact granular structure with grains from 1 to 8 μm in size. The conductivity of the 2-μm-thick electrolyte equals 0.1 S/cm at 650°C.

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Authors and Affiliations

  1. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    E. G. Kalinina & S. V. Scherbinin

  2. Ural Federal University, 620002, Yekaterinburg, Russia

    E. G. Kalinina, E. Yu. Pikalova & S. V. Scherbinin

  3. Institute of High Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    E. Yu. Pikalova

Authors
  1. E. G. Kalinina
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  2. E. Yu. Pikalova
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  3. S. V. Scherbinin
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Correspondence to E. G. Kalinina.

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Translated by V. Isaakyan

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Kalinina, E.G., Pikalova, E.Y. & Scherbinin, S.V. Electrical and Mechanical Properties of CeO2-Based Thin-Film Coatings Obtained by Electrophoretic Deposition. Tech. Phys. 63, 1636–1641 (2018). https://doi.org/10.1134/S1063784218110130

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  • DOI: https://doi.org/10.1134/S1063784218110130

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