Abstract
The preparation method to obtain the new hybrid piezoelectric systems is developed. In it, layer-by-layer oxidative polymerization of aniline is performed in situ on porous polyvinylidene fluoride films prepared by melt extrusion. The formation of conducting form of polyaniline (i.e., emeraldine salt) is confirmed by IR spectroscopy. The samples with double polyaniline layers exhibit a higher electrical conductivity than single-layer ones, with the electrical conductivity growing as the degree of substrate’s orientation increases. The observed effect is related to improved uniformity and structural ordering of the conducting layer, as shown by scanning electron microscopy. The obtained hybrid systems exhibit a higher mechanical strength, elastic modulus, and break elongation, compared to the substrate. The electric and piezoactive properties of prepared samples are studied by cyclic voltammetry and by measuring their piezoelectric modulus; the deposited polyaniline layers served as the contact electrode material in these measurements. The values for piezoelectric coefficients were measured in variuos directions of applied mechanical load.
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REFERENCES
Y. Bar-Cohen and Q. Zhang, MRS Bull. 33, 173 (2008).
A. J. Lovinger, Science (Washington, DC, U. S.) 220, 1115 (1983).
E. Fukada, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 47, 1277 (2000).
A. Salimi and A. A. Yousefi, Polym. Test. 22, 699 (2003).
Y. M. Chang, J. S. Lee, and K. J. Kim, Solid State Phenom. 124, 299 (2007).
P. Martins, A. C. Lopes, and S. Lanceros-Mendez, Prog. Polym. Sci. 39, 683 (2014).
V. V. Kochervinskii, Russ. Chem. Rev. 65, 865 (1996).
I. Yu. Dmitriev, V. K. Lavrentyev, and G. K. Elyashevich, Polymer Sci., Ser. A 48, 272 (2006).
I. Yu. Dmitriev, I. S. Kuryndin, V. K. Lavrentyev, and G. K. Elyashevich, Phys. Solid State 59, 1041 (2017).
I. Yu. Dmitriev, I. S. Kuryndin, and G. K. Elyashevich, RF Patent No. 2635804 (2017).
G. K. Elyashevich, I. S. Kuryndin, I. Yu. Dmitriev, V. K. Lavrentyev, N. N. Saprykina, and V. Bukošek, Chin. J. Polymer Sci. 37, 1283 (2019). https://doi.org/10.1007/s10118-019-2284-2
D. Stauffer and A. Aharony, Introduction to Percolation Theory (Taylor and Francis, London, 1994).
G. K. Elyashevich, E. Yu. Rozova, and E. A. Karpov, RF Patent No. 2140936 (1997).
I. S. Kuryndin, V. K. Lavrentyev, V. Bukošek, and G. K. Elyashevich, Polymer Sci., Ser. A 57, 717 (2015).
A. Stolarczyk, G. K. Elyashevich, E. Yu. Rozova, and M. Lapkowski, Polymer Sci., Ser. A 47, 326 (2005).
A. L. Buyanov, L. G. Revel’skaya, E. Yu. Rosova, and G. K. Elyashevich, J. Appl. Polym. Sci. 94, 1461 (2004).
G. K. Elyashevich, E. Yu. Rosova, D. V. Andreeva, G. A. Polotskaya, M. Trhova, and Z. Pientka, J. Appl. Polym. Sci. 97, 1410 (2005).
A. Bobrovskii, V. P. Shibaev, G. K. Elyashevich, E. Yu. Rosova, A. Shimkin, V. Shirinyan, and K.‑L. Cheng, Polym. Adv. Technol. 21, 100 (2010).
G. K. Elyashevich and M. A. Smirnov, Polymer Sci., Ser. A 54, 900 (2012).
G. K. Elyashevich, I. S. Kuryndin, and E. Yu. Rosova, Polym. Adv. Technol. 13, 725 (2002).
M. Liu, J. Li, and Z. Guo, J. Colloid Interface Sci. 467, 261 (2016).
Y. Fu, H. He, T. Zhao, Y. Dai, W. Han, J. Ma, L. Xing, Y. Zhang, and X. Xue, Nano-Micro Lett. 10, 76 (2018). https://doi.org/10.1007/s40820-018-0228-y
C. S. Lee, J. Joo, S. Han, J. H. Lee, and S. K. Koh, J. Korean Phys. Soc. 45, 747 (2004).
R. Minato, G. Alıcı, S. McGovern, and G. Spinks, Proc. SPIE 6524, 65241J (2007).
S. P. Ozkorucuklu, K. Özdemir, and E. Kır, Polym. Adv. Technol. 23, 1202 (2012).
C. Merlini, G. M. O. Barra, T. M. Araujo, and A. Pegoretti, RSC Adv. 4, 15749 (2014). https://doi.org/10.1039/c4ra01058b
L. F. Malmonge, G. de A. Lopes, S. de C. Langiano, J. A. Malmonge, J. M. M. Cordeiro, and L. H. C. Mattoso, Eur. Polym. J. 42, 3108 (2006).
S. Ray, A. J. Easteal, R. P. Cooney, and N. R. Edmonds, Mater. Chem. Phys. 113, 829 (2009).
E. Yu. Rosova, I. S. Kuryndin, N. V. Bobrova, and G. K. Elyashevich, Polymer Sci., Ser. B 46, 135 (2004).
M. Bleha, M. Trchova, P. Bober, Z. Moravkova, J. Prokes, and J. Stejskal, Mater. Chem. Phys. 194, 206 (2017).
ACKNOWLEDGMENTS
We are grateful to E.N. Vlasova for IR spectroscopy measurements of PVDF and PVDF/PANI samples.
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Elyashevich, G.K., Kuryndin, I.S., Rozova, E.Y. et al. Polymer Piezoelements Based on Porous Polyvinylidene Fluoride Films and Contact Electrode Polyaniline Layers. Phys. Solid State 62, 566–573 (2020). https://doi.org/10.1134/S1063783420030099
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DOI: https://doi.org/10.1134/S1063783420030099