Abstract
The effect of rare-earth ions (R = Er3+, Tb3+) with strong spin-orbit coupling on the dielectric properties and the electric polarization induced by local polar phase separation domains in RMn2O5 multiferroics has been studied. These parameters is found to be qualitatively distinguished from those studied before in GdMn2O5, in which Gd3+ ion in the ground 8S7/2 state is weakly bounded with the lattice. It is shown that the properties of the polar phase separation domains, which form in the subsystem of Mn3+ and Mn4+ ions, are substantially dependent on the values of crystal fields, in which these domains exist.
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Funding
This work was supported by the Russian Foundation for Basic Research (projects nos. 18-32-00241, 20-02-00667) and Program 1.4 of the Presidium of the Russian Academy of Sciences “Topical problems of the low-temperature physics.”
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Translated by Yu. Ryzhkov
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Khannanov, B.K., Golovenchits, E.I. & Sanina, V.A. Effect of Rare-Earth Ions on an Electric Polarization Induced by the Phase Separation Domains in RMn2O5 (R = Er, Tb). Phys. Solid State 62, 308–317 (2020). https://doi.org/10.1134/S1063783420020146
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DOI: https://doi.org/10.1134/S1063783420020146