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Study of the Kinetics of the Phase Transition of the First Order in Tetracosane C24H50 by Fourier-Transform IR Spectroscopy

  • MECHANICAL PROPERTIES, PHYSICS OF STRENGTH, AND PLASTICITY
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Abstract

The kinetics of the development of the structural phase transition of the first order in monodisperse samples of tetracosane C24H50 has been studied using Fourier-transform IR spectroscopy. Temperature dependences of frequencies and intensities of rocking (in the region of  ν ~ 720 cm–1) and bending (in the region of  ν ~ 1470 cm–1) vibration modes of CH2 groups in trans methylene sequences in crystalline cores of elementary lamellae has been analyzed. It has been shown that the solid-phase transition of the first order develops by the heterogeneous mechanism in a narrow temperature interval ΔT ~ 2 K according to the theory of diffuse phase transitions of the first order and is caused by changes in the symmetry of crystallographic cells.

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Funding

This work was supported by Program no. 32 of the Presidium of the Russian Academy of Sciences “Nanostructures: physics, chemistry, biology, and fundamentals of technologies.”

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Authors and Affiliations

  1. Ioffe Institute, 194021, St. Petersburg, Russia

    V. A. Marikhin, S. A. Gur’eva & L. P. Myasnikova

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    B. Z. Volchek & D. A. Medvedeva

Authors
  1. V. A. Marikhin
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  2. S. A. Gur’eva
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  3. L. P. Myasnikova
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  4. B. Z. Volchek
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  5. D. A. Medvedeva
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Corresponding author

Correspondence to V. A. Marikhin.

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The authors declare that they have no conflicts of interest.

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Translated by A. Nikol’skii

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Marikhin, V.A., Gur’eva, S.A., Myasnikova, L.P. et al. Study of the Kinetics of the Phase Transition of the First Order in Tetracosane C24H50 by Fourier-Transform IR Spectroscopy. Phys. Solid State 61, 1785–1789 (2019). https://doi.org/10.1134/S1063783419100251

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  • DOI: https://doi.org/10.1134/S1063783419100251

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