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The Influence of Hydrogenation on the Structure, Magnetic and Magnetocaloric Properties of Tb–Dy–Co Alloys with a Laves Phase Structure

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Abstract

A complex study of structure, phase composition, surface topology, magnetic, and magnetocaloric properties was performed for TbCo2 and Tb0.3Dy0.7Co2 compounds and for a Tb0.3Dy0.7Co2H0.5 hydride with a low hydrogen content. The hydrogenation was established to impact the structural features at the micro- and nanolevels, as well as the fundamental and functional properties. Introducing even a small amount of hydrogen in the crystal lattice of Tb0.3Dy0.7Co2 compound is found to cause an increase in both the Curie temperature and the magnetic moment at the cobalt atoms. The magnetic phase transition from the paramagnetic to the magnetically ordered state changes from the first (in Tb0.3Dy0.7Co2) to the second (in TbCo2 and Tb0.3Dy0.7Co2H0.5) order, leading to a noticeable decrease in the magnetocaloric effect.

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ACKNOWLEDGMENTS

The authors are grateful to H. Drulis for providing a hydrogenation of sample and to D. Gorbunov for help in the organization of measurements under high magnetic fields.

Funding

This work was supported by the Russian Science Foundation (project no. 18-13-00135).

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Authors and Affiliations

  1. Moscow State University, Moscow, Russia

    I. S. Tereshina, T. P. Kaminskaya, V. B. Chzhan, Yu. A. Ovchenkova & A. S. Trusheva

  2. Institute of Experimental Mineralogy, Russian Academy of Sciences, Chernogolovka, Russia

    A. A. Viryus

Authors
  1. I. S. Tereshina
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  2. T. P. Kaminskaya
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  3. V. B. Chzhan
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  4. Yu. A. Ovchenkova
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  6. A. A. Viryus
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Correspondence to I. S. Tereshina.

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Translated by O. Maslova

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Tereshina, I.S., Kaminskaya, T.P., Chzhan, V.B. et al. The Influence of Hydrogenation on the Structure, Magnetic and Magnetocaloric Properties of Tb–Dy–Co Alloys with a Laves Phase Structure. Phys. Solid State 61, 1169–1175 (2019). https://doi.org/10.1134/S1063783419070278

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  • DOI: https://doi.org/10.1134/S1063783419070278

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