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Rise Kinetics of Up-Conversion Luminescence of the LiY0.8Yb0.2F4:Tm3+ (0.2 at %) Crystal with Pulsed Excitation

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Abstract

The regression analysis of the rise kinetics of up-conversion luminescence of the LiY0.8Yb0.2F4:Tm3+ (0.2 at %) crystal is performed. The kinetics curve is obtained with rectangular pulsed excitation by radiation from a laser diode (IR LD) with a wavelength of λp = 933 nm. The most important—in these experimental conditions—mechanisms of the energy transfer from Yb3+ ions to Tm3+ ions are established, which are responsible for the transitions between the ground 3H6 and excited 3F4, 3H4, 1G4, 1D2, and 1I6 terms of the Tm3+ ions. The durations of the relevant energy transfer processes are determined. It is shown that the energy transfer between rare earth ions in the LiY0.8Yb0.2F4:Tm3+ (0.2 at %) crystal occurs through the dipole–dipole interactions.

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FUNDING

The work was supported by the subsidy allocated to Kazan Federal University to perform the State assignment in the field of scientific activity (project no. 3.1156.2017/4.6).

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Authors and Affiliations

  1. Kazan National Research Technological University, Kazan, Russia

    A. V. Mikheev

  2. Kazan Federal University, Kazan, Russia

    B. N. Kazakov

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  1. A. V. Mikheev
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  2. B. N. Kazakov
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Correspondence to A. V. Mikheev.

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Translated by O. Kadkin

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Mikheev, A.V., Kazakov, B.N. Rise Kinetics of Up-Conversion Luminescence of the LiY0.8Yb0.2F4:Tm3+ (0.2 at %) Crystal with Pulsed Excitation. Phys. Solid State 61, 860–866 (2019). https://doi.org/10.1134/S1063783419050172

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  • DOI: https://doi.org/10.1134/S1063783419050172

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