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Transferability of Crystal-Field Parameters for Rare-Earth Ions in Y2SiO5 Tested by Zeeman Spectroscopy

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Abstract

Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two C1 point-group symmetry sites in Er3+:Y2SiO5 may be transferred to other ions. The two crystallographic six-and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.

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Authors and Affiliations

  1. School of Physical and Chemical Sciences, University of Canterbury, PB 4800, Christchurch, New Zealand

    N. L. Jobbitt, S. J. Patchett, Y. Alizadeh, M. F. Reid, J.-P. R. Wells & S. P. Horvath

  2. The Dodd-Walls Centre for Photonic and Quantum Technologies, Dunedin, New Zealand

    N. L. Jobbitt, S. J. Patchett, Y. Alizadeh, M. F. Reid & J.-P. R. Wells

  3. Department of Physics, University of Otago, Dunedin, New Zealand

    S. P. Horvath & J. J. Longdell

  4. Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris, Paris, France

    J. J. Longdell & A. Ferrier

  5. Faculté des Sciences et Ingénierie, Sorbonne Université, Paris, France

    A. Ferrier & P. Goldner

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  1. N. L. Jobbitt
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  2. S. J. Patchett
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  4. M. F. Reid
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  6. S. P. Horvath
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  7. J. J. Longdell
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  8. A. Ferrier
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Correspondence to M. F. Reid.

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Jobbitt, N.L., Patchett, S.J., Alizadeh, Y. et al. Transferability of Crystal-Field Parameters for Rare-Earth Ions in Y2SiO5 Tested by Zeeman Spectroscopy. Phys. Solid State 61, 780–784 (2019). https://doi.org/10.1134/S1063783419050123

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  • DOI: https://doi.org/10.1134/S1063783419050123

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