Abstract
The EPR spectrum of an Eu2+ impurity center in a SrMoO4 single crystal in the temperature range T = 1.8, 111–300 K has been studied, and the temperature changes in the spin Hamiltonian parameters describing the EPR spectrum of odd europium isotopes have been determined. It is shown that small temperature changes in the diagonal parameters of the spin Hamiltonian (for odd Eu2+ isotopes) \(b_{2}^{0}\)(T) = b2(F) + b2(L) and \(P_{2}^{0}\)(T) = P2(F) + P2(L) are explained by the compensation of spin–phonon contributions b2(F) and P2(F) by the contributions of the lattice thermal expansion b2(L) and P2(L). The quantities b2(L) and P2(L) that are dependent on the static lattice parameters at a given temperature, are estimated in terms of the superposition Newman model. Then, the spin–phonon b2(F) and P2(F) contributions determined by the lattice ion vibrations are separated. An analysis shows that \(b_{2}^{0}\)(F) and \(P_{2}^{0}\)(F) > 0, b2(L) and P2(L) < 0, and the temperature behavior of the spin–phonon contribution is well described by G. Pfister’s model of local vibrations.
Similar content being viewed by others
REFERENCES
Th. P. J. Botden, Philips Res. Rep. 6, 425 (1951).
A. Kaminskii, H. J. Eichler, K. Ueda, N. V. Klassen, B. S. Redkin, L. E. Li, J. Findeisen, D. Jaque, J. Garcia-Sole, J. Fernandez, and R. Balda, Appl. Opt. 38, 4533 (1999).
V. Osiko and I. Shcherbakov, Fotonika 39, 14 (2013).
P. Meunier, M. Bravin, M. Bruckmayer, S. Giordano, M. Loidl, O. Meier, F. Pröbst, W. Seidel, M. Sisti, L. Stodolsky, S. Uchaikin, and L. Zerle, Appl. Phys. Lett. 75, 1335 (1999).
W. M. Walsh, Jr., Phys. Rev. 114, 1473 (1959).
A. D. Gorlov, Phys. Solid State 57, 1394 (2015).
A. D. Gorlov, Phys. Solid State 59, 578 (2017).
A. D. Gorlov, Phys. Solid State 60, 334 (2018).
W. M. Walsh, Jr., J. Jeener, and N. Bloembergen, Phys. Rev. A 139, 1338 (1965).
D. J. Newman, J. Phys. C 8, 1862 (1975).
L. I. Levin and A. D. Gorlov, J. Phys.: Condens. Matter 4, 1981 (1992).
B. Bleaney, in Superfine Interactions in Solids, Ed. E. A. Turov (Mir, Moscow, 1970), p. 15 [in Russian].
A. Abragam and B. Bleaney, Electron Paramagnetic Resonance of Transition Ions (Oxford Univ., London, 1970), Vol. 1.
A. D. Gorlov, Phys. Solid State 56, 2185 (2014).
S. A. Altshuler and B. M. Kozyrev, Electron Paramagnetic Resonance in Compounds of Transition Elements (Wiley, New York, 1974; Nauka, Moscow, 1972).
V. A. Vazhenin, A. D. Gorlov, L. I. Levin, K. M. Starichenko, S. A. Chikin, and K. M. Eriksonas, Sov. Phys. Solid State 29, 1744 (1987).
W. C. Zheng and S. Y. Wu, Phys. B (Amsterdam, Neth.) 304, 137 (2001).
R. D. Shennon, Acta Crystallogr., A 32, 751 (1976).
G. Guthohrlein, Physik 214, 332 (1968).
T. Rewaijt, J. Kuriata, J. Typek, and J. Y. Buzare, Acta Phys. Polon. A 84, 1143 (1993).
C. Y. Huang, Phys. Rev. 159, 683 (1967).
K. N. Shrivastava, Phys. Rev. 187, 446 (1969).
G. Pfister, W. Draybrodt, and W. Assmus, Phys. Status Solidi B 36, 351 (1969).
FUNDING
This work was carried out in the framework of the state task of the Ministry of Education and Science of the Russian federation for Ural Federal University (state task 3.6115.2017/8.9) on the equipment of the Collective Use Center “Modern nanotechnologies” at UrFU.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by Yu. Ryzhkov
Rights and permissions
About this article
Cite this article
Gorlov, A.D. Static and Dynamic Contributions to the Splitting of the Eu2+ Ground State in SrMoO4. Phys. Solid State 61, 802–805 (2019). https://doi.org/10.1134/S106378341905010X
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S106378341905010X