Skip to main content
Log in

Superhyperfine Structure of the EPR Spectra of Nd3+ Impurity Ions in Fluorite CaF2

  • Dielectrics
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

EPR spectra of a CaF2 single crystal that was grown from melt containing a small addition of NdF3 were studied. Signals corresponding to tetragonal centers of Nd3+ ions and cubic centers of Er3+ and Yb3+ ions were found. Superhyperfine structure (SHFS) in the spectra of the Nd3+ ions was observed for the first time in this crystal; parameters of the superhyperfine interaction of the Nd3+ ions with the nearest nine fluorine ions were determined. The dependence of the resolution of the Nd3+ EPR spectrum SHFS on the incident microwave power at the temperature of T ≈ 6 K was studied. Obtained results are discussed and compared with the literature data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. A. Altshuler and B. M. Kozyrev, Electron Paramagnetic Resonance of Compounds of Elements of Intermediate Groups (Nauka, Moscow, 1972) [in Russian].

    Google Scholar 

  2. A. Abragam and B. Bleaney, Electron Paramagnetic Resonance of Transition Ions (Oxford Univ., London, 1970), Vol. 2.

  3. L. K. Aminov, I. N. Kurkin, and B. Z. Malkin, Phys. Solid State 55, 1343 (2013).

    Article  ADS  Google Scholar 

  4. B. Bleaney, P. M. Llewellyn, and D. A. Jones, Proc. Phys. Soc. London, B 69, 858 (1956).

    Article  ADS  Google Scholar 

  5. J. M. Baker, W. Hayes, and M. C. M. O’Brien, Proc. R. Soc. A 254, 273 (1960).

    Article  ADS  Google Scholar 

  6. B. G. Berulava, T. I. Sanadze, and O. G. Khakhanishvili, Sov. Phys. JETP 21, 288 (1965).

    ADS  Google Scholar 

  7. L. K. Aminov, A. A. Ershova, S. L. Korableva, I. N. Kurkin, B. Z. Malkin, and A. A. Rodionov, Phys. Solid State 53, 2240 (2011).

    Article  ADS  Google Scholar 

  8. L. K. Aminov, M. R. Gafurov, S. L. Korableva, I. N. Kurkin, and A. A. Rodionov, Phys. Solid State 57, 2400 (2015).

    Article  ADS  Google Scholar 

  9. U. Ranon and J. S. Hyde, Phys. Rev. 141, 259 (1966).

    Article  ADS  Google Scholar 

  10. T. T. Basiev, V. V. Fedorov, Yu. V. Orlovskii, K. K. Pukhov, A. Ya. Karasik, I. N. Kurkin, S. P. Kurzin, D. A. Lukoyanov, and J. Heber, in Proceedings of the 11th Feofilov Symposium on Spectroscopy of Crystals Activated by Rare Earth Ions, Kazan, 2001, Abstracts PF-18.

    Google Scholar 

  11. N. E. Kask, L. S. Kornienko, and M. Fakir, Sov. Phys. Solid State 6, 430 (1964).

    Google Scholar 

  12. N. E. Kask, L. S. Kornienko, and E. G. Lariontsev, Sov. Phys. Solid State 8, 2058 (1966).

    Google Scholar 

  13. M. J. Weber and R. W. Bierig, Phys. Rev. A 134, 1492 (1964).

    Article  ADS  Google Scholar 

  14. S. M. Arkhipov and B. Z. Malkin, Sov. Phys. Solid State 22, 857 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. R. Gafurov.

Additional information

Original Russian Text © L.K. Aminov, M.R. Gafurov, I.N. Kurkin, B.Z. Malkin, A.A. Rodionov, 2018, published in Fizika Tverdogo Tela, 2018, Vol. 60, No. 5, pp. 910–913.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aminov, L.K., Gafurov, M.R., Kurkin, I.N. et al. Superhyperfine Structure of the EPR Spectra of Nd3+ Impurity Ions in Fluorite CaF2. Phys. Solid State 60, 912–915 (2018). https://doi.org/10.1134/S1063783418050037

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783418050037

Navigation