Abstract
The electron paramagnetic resonance (EPR) spectra of iron-doped ZnSe single crystals were studied. In addition to cubic Fe3+ and Mn2+ centers and also Fe2+, and Cr2+ centers, monoclinic Fe3+ complexes locally compensated by Cu+ ions were revealed. Some trigonal centers with a spin of 3/2 were also found and studied. The zero-field splittings of monoclinic centers were measured, and the parameters of the monoclinic and trigonal spin Hamiltonians were determined. The nature of trigonal centers was discussed.
Similar content being viewed by others
References
D. D. Kramushchenko, I. V. Ilyin, V. A. Soltamov, P.G. Baranov, V. P. Kalinushkin, M. I. Studenikin, V. P. Danilov, N. N. Il’ichev, and P. V. Shapkin, Phys. Solid State 55, 269 (2013).
G. Colibaba, M. Caraman, I. Evtodiev, S. Evtodiev, E. Goncearenco, D. Nedeoglo, and N. Nedeoglo, J. Lumin. 145, 237 (2014).
V. I. Kozlovskii, Yu. V. Korostelin, and Ya. K. Skasyrskii, in Proceedings of the 11th Russian Conference on Semiconductor Physics, St. Petersburg, 2013, p.144.
G. S. Shakurov, D. S. Pytalev, V. I. Kozlovskii, and Yu. V. Korostelin, in Proceedings of the 21st All-Russia Conference on Optics and Spectroscopy of Condensed Media, Krasnodar, 2015, p.20.
Y. V. Korostelin and V. I. Kozlovsky, J. Alloys Compd. 371, 25 (2004).
R. S. Title, Phys. Rev. 131, 2503 (1963).
W. C. Holton, M. de Wit, T. L. Estle, B. Dischler, and J. Schneider, Phys. Rev. 169, 359 (1968).
N. Sielaff, H. Nelkowski, H. Pradella, J. Sahm, and K. Zink, Phys. Status Solidi B 129, K177 (1985).
S. A. Al’tshuler and B. M. Kozyrev, Electron Paramagnetic Resonance of Compounds of Elements of the Intermediate Groups (Nauka, Moscow, 1972), p. 121 [in Russian].
J. T. Vallin and G. D. Watkins, Phys. Rev. B 9, 2051 (1974).
M. E. J. Boonman, W. Mac, A. Twardowski, A. Wittlin, P. J. M. van Bentum, J. C. Maan, and M. Demianiuk, Phys. Rev. B 61, 5358 (2000).
A. T. Lonchakov, S. M. Podgornykh, V. I. Sokolov, N. B. Gruzdev, and G. S. Shakurov, Phys. Solid State 48, 1703 (2006).
Ya. G. Klyava, EPR-Spectroscopy of Disordered Solids (Zinatne, Riga, 1988) [in Russian].
R. W. Kedzie, D. H. Lyons, and M. Kestigian, Phys. Rev. A 138, 918 (1965).
H. H. Wickman, M. P. Klein, and D. A. Shirley, J. Chem. Phys. 42, 2113 (1965).
N. S. Garif’yanov and M. M. Zaripov, Sov. Phys. JETP 1, 567 (1955).
W. C. Holton, J. Schneider, and T. L. Estle, Phys. Rev. A 133, 1638 (1964).
S. A. Marshall and S. V. Nistor, Phys. Rev. B 6, 24 (1972).
S. V. Nistor, M. Stefan, and D. Schoemaker, Phys. Status Solidi B 214, 229 (1999).
H. Vrielinck, F. Callens, P. Matthys, S. V. Nistor, D. Ghica, and D. Schoemaker, Phys. Rev. B 64, 024405 (2001).
M. M. Zaripov, V. S. Kropotov, L. D. Livanova, and V. G. Stepanov, Sov. Phys. Solid State 9, 155 (1967).
M. M. Zaripov, V. S. Kropotov, L. D. Livanova, and V. G. Stepanov, Sov. Phys. Solid State 10, 262 (1968).
L. K. Aminov and B. Z. Malkin, Sov. Phys. Solid State 9, 1030 (1967).
J. Dieleman, Philips Res. Rep. 20, 206 (1965).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.A. Vazhenin, A.P. Potapov, G.S. Shakurov, A.V. Fokin, M.Yu. Artyomov, V.I. Kozlovskii, Yu.V. Korostelin, D.S. Pytalev, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 10, pp. 1970–1977.
Rights and permissions
About this article
Cite this article
Vazhenin, V.A., Potapov, A.P., Shakurov, G.S. et al. Paramagnetic defects in ZnSe crystals doped with iron ions. Phys. Solid State 59, 1993–2001 (2017). https://doi.org/10.1134/S106378341710033X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S106378341710033X