Abstract
The results of the Mössbauer studies on 57Fe nuclei in multiferroics BiFe1–x T x O3 (T = Sc, Mn; x = 0, 0.05) in the temperature range of 5.2–300 K have been presented. The Mössbauer spectra have been analyzed in terms of the model of an incommensurate spatial spin-modulated structure of cycloid type. Information has been obtained about the effect of the substitution of Sc and Mn atoms for Fe atoms on the hyperfine parameters of the spectrum: the shift and the quadrupole shift of the Mössbauer line, the isotropic and anisotropic contributions to the hyperfine magnetic field, and also the parameter of anharmonicity of the spatial spin-modulated structure.
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Original Russian Text © V.S. Rusakov, V.S. Pokatilov, A.S. Sigov, M.E. Matsnev, A.M. Gapochka, T.Yu. Kiseleva, A.E. Komarov, M.S. Shatokhin, A.O. Makarova, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 1, pp. 102–107.
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Rusakov, V.S., Pokatilov, V.S., Sigov, A.S. et al. Spatial spin-modulated structure and hyperfine interactions of 57Fe nuclei in multiferroics BiFe1–x T x O3 (T = Sc, Mn; x = 0, 0.05). Phys. Solid State 58, 102–107 (2016). https://doi.org/10.1134/S1063783416010261
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DOI: https://doi.org/10.1134/S1063783416010261