Abstract
The result of low-background measurements of the gamma activity of graphite-potassium intercalated sample is presented. A germanium gamma spectrometer, used for measurements, was located in the low-background chamber of Baksan Neutrino Observatory. For 384 hours of exposure, 768 decays of K-40 isotope nuclei were registered. This activity corresponds to 85 μg/cm2 potassium atoms embedded in to graphite lattice. A computer simulation of the intercalation process and the gamma-ray spectrum set is also presented. The accuracy of the potassium concentration determination can be brought to 10–11–10–12 g/g for mixture enriched with K-40 isotope.
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REFERENCES
D. R. Cooper, B. D’Anjou, N. Ghattamaneni, B. Harack, M. Hilke, A. Horth., N. Majlis, M. Massicotte, L. Vandsburger, E. Whiteway, and V. Yu, “Experimental review of graphene,” Condens. Matter Phys. 2012, 56 (2012).
Z. A. Akhmatov, A. Kh. Khokonov, and V. A. Tarala, “Vibrational dynamics of pristine and the hydrogenated graphene surface,” Bull. Russ. Acad. Sci.: Phys. 80, 1341–1343 (2016).
D. Budjase, A. M. Gangapshev, V. V. Kuzminov, J. Gasparro, W. Hampel, M. Heisel, G. Heusser, M. Hult, M. Laubenstein, W. Maneschg, H. Simgen, A. A. Smolnikov, C. Tomei, and S. I. Vasiliev, “Gamma-ray spectrometry of ultra low levels of radioactivity within the material screening program for the GERDA experiment,” Appl. Radiat. Isot. 67, 755–758 (2009).
V. V. Kuzminov, V. V. Alekseenko, I. R. Barabanov, R. A. Etezov, A. M. Gangapshev, Yu. M. Gavrilyuk, A. M. Gezhaev, V. V. Kazalov, A. Kh. Khokonov, S. I. Panasenko, and S. S. Ratkevich, “Some features and results of thermal neutron background measurements with the [ZnS(Ag) + 6 LiF] scintillation detector,” Nucl. Instrum. Methods A 841, 156–161 (2017).
S. Plimpton, “Fast parallel algorithms for short-range molecular dynamics,” J. Comput. Phys. 117, 1–19 (1995).
J. Tersoff, “Empirical interatomic potential for carbon, with applications to amorphous carbon,” Phys. Rev. Lett. 61, 2879–2882 (1988).
M. S. Daw and M. I. Baskes, “Embedded atom method: Derivation and application to impurities, surfaces, and other defects in metals,” Phys. Rev. B 29, 6443–6453 (1984).
S. M. Foiles, M. I. Baskes, and M. S. Daw, “Embedded atom method functions for the fcc metals Cu, Ag, Au, Ni, Pd, Pt, and their alloys,” Phys. Rev. B 33, 7983–7991 (1986).
J. Purewal, J. B. Keith, C. A. Channing, C. M. Brown, M. Tyagi, and B. J. Fultz, “Hydrogen diffusion in potassium intercalated graphite studied by quasielastic neutron scattering,” J. Chem. Phys. 137, 1–10 (2012).
HyperChem for Windows Reference Manual (Hypercube, Inc., 1999). http://www.hyper.com.
S. Agostinelli, J. Allison, K. Amako, J. Apostolakis, H. Araujo, P. Arce, M. Asai, D. Axen, S. Banerjee, G. Barrand, F. Behner, L. Bellagamba, J. Boudreau, L. Broglia, A. Brunengo, and H. Burkhardt, “Geant4—a simulation toolkit,” Nucl. Instrum. Methods Phys. Res., Sect. A 506, 250–303 (2003).
ACKNOWLEDGMENTS
The work was supported partially by grants: RFBR no. 16-29-13011 ofi_m, RFBR no. 18-02-01042 a and Foundation for Assistance to Small Innovative Enterprises no. 0038507 UMNIK 17-12 (a).
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Ahmatov, Z.A., Gangapshev, A.M., Romanenko, V.S. et al. Low-Background Method of Isotope Markers for Measuring the Efficiency of Intercalation of Graphite by Potassium Atoms. Phys. Part. Nuclei 49, 787–792 (2018). https://doi.org/10.1134/S1063779618040032
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DOI: https://doi.org/10.1134/S1063779618040032