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Electron Paramagnetic Resonance of Cr3+ Ions in ABO3 (A = Sc, In, Ga) Diamagnetic Crystals

  • ORDER, DISORDER, AND PHASE TRANSITION IN CONDENSED SYSTEM
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Abstract

A magnetic resonance method is applied to the investigation of a number of isostructural diamagnetic compounds ABO3 (A = Sc, In, and Ga) with small additions of Cr3+ ions (S = 3/2) sufficient to observe single-ion and pair spectra. It is shown that the resonance spectra for isolated Cr3+ ions can be described to a good accuracy by the ordinary axial spin Hamiltonian for 3d ions in octahedral oxygen environment. The parameters of the spin Hamiltonian are determined for single Cr3+ ion and Cr3+–Cr3+ pair. Lattice distorsions of the parent ABO3 crystals caused by the Cr3+ impurities is discussed.

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Authors and Affiliations

  1. Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center,” Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

    A. M. Vorotynov, V. V. Rudenko, S. G. Ovchinnikov & M. S. Molokeev

  2. Siberian Federal University, 660041, Krasnoyarsk, Russia

    M. S. Molokeev

Authors
  1. A. M. Vorotynov
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  2. V. V. Rudenko
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  3. S. G. Ovchinnikov
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  4. M. S. Molokeev
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Correspondence to A. M. Vorotynov.

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Vorotynov, A.M., Rudenko, V.V., Ovchinnikov, S.G. et al. Electron Paramagnetic Resonance of Cr3+ Ions in ABO3 (A = Sc, In, Ga) Diamagnetic Crystals. J. Exp. Theor. Phys. 127, 1067–1073 (2018). https://doi.org/10.1134/S1063776118120245

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  • DOI: https://doi.org/10.1134/S1063776118120245

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