Skip to main content
SpringerLink
Log in

Mössbauer and Magnetic Study of Lanthanum Manganite La1 – xCaxMn0.98Fe0.02O3 + δ (x = 0.05, 0.10, 0.20): Nonstoichiometric and Stoichiometric Composition

  • PROCEEDINGS OF THE XV INTERNATIONAL CONFERENCE “MÖSSBAUER SPECTROSCOPY AND ITS APPLICATIONS”
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

Mössbauer and magnetic study of calcium-doped lanthanum manganites La1 – xCaxMn0.98Fe0.02O3 + δ (x = 0.05, 0.10, 0.20) of nonstoichiometric (LCM–NS) and stoichiometric (LCM–S) compositions have been carried out in a wide temperature range. Phase structural separation is observed in the samples of stoichiometric composition (δ = 0). With a decrease in temperature all investigated lanthanum manganite samples exhibit superparamagnetic behavior, caused by the formation of small magnetic clusters in the structure. An expansion of the concentration range toward lower dopant concentrations in the LCM–S samples allowed us to establish the competing processes occurring at a low Ca content, including the Jahn‒Teller effects (orbital order) and the presence of Mn4+ ions (violation of orbital order), and study the dynamics of the structure and magnetic properties as functions of the Ca content.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. M. B. Salamon and M. Jaime, Rev. Mod. Phys. 73, 583 (2001).

    Article  ADS  Google Scholar 

  2. E. L. Nagaev, Usp. Fiz. Nauk 66 (8), 833 (1996).

    Article  Google Scholar 

  3. J. M. Ralph, J. T. Vaughey, and M. Krumpelt, Proc. Seventh Int. Symposium “Solid Oxide Fuel Cells,” Ed. by H. Yokokawa and S. C. Singhal (Electrochemical Society, Pennington, New Jersey, 2001), p. 466.

  4. K. Huang, J. Wang, and J. B. Goodenough, J. Mater. Sci. 36, 1093 (2001).

    Article  ADS  Google Scholar 

  5. V. D. Sedykh, V. S. Rusakov, I. I. Zver’kova, et al., Phys. Solid State 53 (7), 1440 (2011).

    Article  ADS  Google Scholar 

  6. M. E. Matsnev and V. S. Rusakov, AIP Conf. Proc. 1489, 178 (2012).

    Article  ADS  Google Scholar 

  7. V. Sedykh, V. Sh. Shekhtman, I. I. Zverkova, et al., Physica C 433, 189 (2006).

    Article  ADS  Google Scholar 

  8. V. Sedykh, G. E. Abrosimova, V. Sh. Shekhtman, et al., Physica C 418, 144 (2005).

    Article  ADS  Google Scholar 

  9. V. D. Sedykh, AIP Conf. Proc. 1622, 72 (2014).

    Article  ADS  Google Scholar 

  10. D. I. Pchelina, I. Yu. Medvetskaya, N. I. Chistyakova, et al., Poverkhnost, No. 11, 3 (2018).

    Google Scholar 

  11. D. I. Pchelina, I. Yu. Medvetskaya, N. I. Chistyakova, et al., Poverkhnost, No. 6, 3 (2019).

    Google Scholar 

  12. B. Hannoyer, G. Marest, J. M. Greneche, et al., Phys. Rev. B 61, 9613 (2000).

    Article  ADS  Google Scholar 

  13. H. Song, W. Kim, S.-J. Kwon, and J. Kang, J. Appl. Phys. 89, 3398 (2001).

    Article  ADS  Google Scholar 

  14. J. Topfer and J. B. Goodenough, J. Solid State Chem. 130, 117 (1997).

    Article  ADS  Google Scholar 

  15. J. S. Kouvel, J. Phys. Chem. Solids 21 (1–2), 57 (1961).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    V. D. Sedykh

  2. Moscow State University, 119991, Moscow, Russia

    I. Yu. Medvetskaya, D. I. Pchelina, N. I. Chistyakova, V. S. Rusakov & Yu. A. Alekhina

Authors
  1. V. D. Sedykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. Yu. Medvetskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. I. Pchelina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. I. Chistyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. S. Rusakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yu. A. Alekhina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. D. Sedykh.

Additional information

Translated by E. Bondareva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sedykh, V.D., Medvetskaya, I.Y., Pchelina, D.I. et al. Mössbauer and Magnetic Study of Lanthanum Manganite La1 – xCaxMn0.98Fe0.02O3 + δ (x = 0.05, 0.10, 0.20): Nonstoichiometric and Stoichiometric Composition. Crystallogr. Rep. 65, 347–351 (2020). https://doi.org/10.1134/S1063774520030293

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774520030293

Search

Navigation