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Crystallography of the Destruction Fragments of Tubular Cyanine Dye J-Aggregates on the Mica Surface

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Abstract

A crystallographic analysis of the images of destruction fragments of tubular monomethine dye J-aggregates has been performed for the first time. It is shown that the formation of characteristic zigzag fragments is caused by the unwrapping of cylindrical surface on plane. Possible cleavage directions for the monolayer forming the tube walls are considered and an interrelation between the destruction products and molecular packing of this monolayer is established.

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ACKNOWLEDGMENTS

The analytical studies (AFM measurements) were carried out on the equipment (EnviroScope atomic force microscope with a Nanoscope-V controller (Veeco, US)) of the Center for Collective Use of Physical Investigation Methods at the Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences.

Funding

This work was supported by the Russian Foundation for Basic Research (project 17-03-01179 A).

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, 119071, Moscow, Russia

    S. I. Pozin, V. V. Prokhorov, O. M. Perelygina & E. I. Mal’tsev

Authors
  1. S. I. Pozin
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  2. V. V. Prokhorov
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  3. O. M. Perelygina
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  4. E. I. Mal’tsev
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Corresponding author

Correspondence to S. I. Pozin.

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Translated by E. Bondareva

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Pozin, S.I., Prokhorov, V.V., Perelygina, O.M. et al. Crystallography of the Destruction Fragments of Tubular Cyanine Dye J-Aggregates on the Mica Surface. Crystallogr. Rep. 64, 639–643 (2019). https://doi.org/10.1134/S1063774519040151

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  • DOI: https://doi.org/10.1134/S1063774519040151

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