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Bis(nitrilo)tris(methylenephosphonato)dodecaaquatrihydrohexasodium Europium(III) [EuNa6H3(H2O)12{N(CH2PO3)3}2]: Synthesis and Structure

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Abstract

The crystal structure of bis(nitrilo)tris(methylenephosphonato)dodecaaquatrihydrohexasodium europium(III) [EuNa6H3(H2O)12{N(CH2PO3)3}2] was determined; sp. gr. \(P\bar 1\), Z = 2, a = 11.0801(3) Å, b = 11.5992(3) Å, c = 14.6879(4) Å, α = 70.096(3)°, β = 77.730(2)°, γ = 80.452(2)°. The coordination polyhedron of the Eu atom can be described as a distorted dodecadeltahedron (snub disphenoid), with two vertices occupied by nitrogen atoms of two phosphonate ligands and the other six vertices occupied by oxygen atoms of six PO3 groups. The chelate complex contains six five-membered rings Eu–O–P–C–N and six eight-membered rings Eu–O–P–C–N–C–P–O.

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Authors and Affiliations

  1. Lobachevsky National Research University, Nizhny Novgorod, 603950, Russia

    N. V. Somov

  2. Physical-Technical Institute, Ural Branch of the Russian Academy of Sciences, Izhevsk, 426000, Russia

    F. F. Chausov

  3. Udmurt State University, Izhevsk, 426034, Russia

    F. F. Chausov & R. M. Zakirova

  4. Institute of Mechanics, Ural Branch of the Russian Academy of Sciences, Izhevsk, 426067, Russia

    F. F. Chausov, M. A. Shumilova, V. G. Petrov & D. K. Zhirov

Authors
  1. N. V. Somov
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  2. F. F. Chausov
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  3. R. M. Zakirova
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  4. M. A. Shumilova
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  5. V. G. Petrov
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  6. D. K. Zhirov
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Correspondence to N. V. Somov.

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Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, M.A. Shumilova, V.G. Petrov, D.K. Zhirov, 2018, published in Kristallografiya, 2018, Vol. 63, No. 3, pp. 415–422.

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Somov, N.V., Chausov, F.F., Zakirova, R.M. et al. Bis(nitrilo)tris(methylenephosphonato)dodecaaquatrihydrohexasodium Europium(III) [EuNa6H3(H2O)12{N(CH2PO3)3}2]: Synthesis and Structure. Crystallogr. Rep. 63, 364–371 (2018). https://doi.org/10.1134/S1063774518030276

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