Skip to main content
SpringerLink
Log in

The Influence of Cation Substitution on the Kinetics of Phase Transitions in Crystals of (K,NH4)3H(SO4)2 Solid Solutions

  • Structure of Inorganic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The structure of (K0.967(NH4)0.033)3H(SO4)2 crystals, belonging to the K3H(SO4)2–(NH4)3H(SO4)2–H2O salt system, has been investigated by X-ray structural analysis. The room-temperature characteristics of the atomic structure of these crystals are found to be as follows: sp. gr. C2/c, Z = 4, a = 14.7025(4) Å, b = 5.6859(2) Å, c = 9.7885(3) Å, and R/wR = 0.021/0.030%. The thermal and optical properties of (K,NH4)3H(SO4)2 and K3H(SO4)2 single crystals have been investigated and compared in a temperature range of 295–500 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. V. Dmitricheva, I. P. Makarova, V. V. Grebenev, et al., Crystallogr. Rep. 59 (3), 344 (2014).

    Article  ADS  Google Scholar 

  2. E. V. Dmitricheva, I. P. Makarova, V. V. Grebenev, et al., Crystallogr. Rep. 59 (6), 878 (2014).

    Article  ADS  Google Scholar 

  3. E. V. Dmitricheva, I. P. Makarova, V. V. Grebenev, et al., Solid State Ionics 268, 68 (2014).

    Article  Google Scholar 

  4. E. V. Dmitricheva, I. P. Makarova, V. V. Grebenev, et al., Crystallogr. Rep. 60 (6), 814 (2015).

    Article  ADS  Google Scholar 

  5. A. I. Baranov, Crystallogr. Rep. 48 (6), 1012 (2003).

    Article  ADS  Google Scholar 

  6. A. K. Ivanov-Shits and I. V. Murin, Solid-State Ionics, Vol. 2 (Izd-vo SPbGU, St. Petersburg, 2010) [in Russian].

  7. A. I. Baranov, V. V. Grebenev, U. Bismaer, and J. Ludwig, Ferroelectrics 369, 108 (2008).

    Article  Google Scholar 

  8. I. P. Makarova, T. S. Chernaya, I. A. Verin, et al., Phys. Solid State 51 (7), 1431 (2009).

    Article  ADS  Google Scholar 

  9. I. P. Makarova, T. S. Chernaya, A. A. Filaretov, et al., Crystallogr. Rep. 55 (3), 393 (2010).

    Article  ADS  Google Scholar 

  10. S. Suzuki and Y. Makita, Acta Crystallogr. B 34, 732 (1978).

    Article  Google Scholar 

  11. T. Fukami, K. Horiuchi, K. Nakasone, and K. Furukawa, Jpn J. Appl. Phys. 35, 2253 (1996).

    Article  ADS  Google Scholar 

  12. Oxford Diffraction. CrysAlisPro (Oxford Diffraction Ltd, Yarnton, Oxfordshire, UK, 2011).

  13. V. Petříček, M. Dušek, and L. Palatinus, Z. Kristallogr. 229, 345 (2014).

    Google Scholar 

  14. P. J. Becker and P. Coppens, Acta Crystallogr. A 30, 129 (1974).

    Article  ADS  Google Scholar 

  15. K. Brandenburg and H. Putz, DIAMOND, Version 3 (Crystal Impact GbR, Bonn, Germany, 2005).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”, Russian Academy of Sciences, Moscow, 119333, Russia

    E. V. Selezneva, I. P. Makarova, V. V. Grebenev & V. A. Komornikov

Authors
  1. E. V. Selezneva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. P. Makarova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Grebenev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Komornikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. V. Selezneva.

Additional information

Original Russian Text © E.V. Selezneva, I.P. Makarova, V.V. Grebenev, V.A. Komornikov, 2018, published in Kristallografiya, 2018, Vol. 63, No. 2, pp. 195–202.

First Russian Crystallographic Congress

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Selezneva, E.V., Makarova, I.P., Grebenev, V.V. et al. The Influence of Cation Substitution on the Kinetics of Phase Transitions in Crystals of (K,NH4)3H(SO4)2 Solid Solutions. Crystallogr. Rep. 63, 178–185 (2018). https://doi.org/10.1134/S1063774518020244

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774518020244

Search

Navigation