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Structure of a new three-dimensional metal-organic framework: Poly[manganese(II)-bis-(µ4-1,4-naphthalenedicarboxylate)-bis-(N,N-dimethylformamide)]

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Abstract

A novel metal-organic framework, [Mn2(C12H6O4)2(C3H7NO)2] n has been synthesized solvothermally by assembling ligands 1,4-naphthalenedicarboxylic acid (NDC), N,N-dimethylformamide (DMF) and manganese(II). Both independent Mn(II) ions are six-coordinated in a distorted octahedral environment with oxygen donors. Bis(bridging bidentate) μ4-η1:η1:η2:η1, NDC ligands orient in two directions, [010] and [001], linking the Mn(II) ions to form a square grid in (100) plane. Corner shared Mn(II) octahedral form chains along a direction resulting in a three dimensional network.

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Authors and Affiliations

  1. Department of Chemistry, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan University, Kunming, 650091, People’s Republic of China

    Q. Wang, T. Yan & L. Du

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  1. Q. Wang
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  2. T. Yan
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  3. L. Du
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Correspondence to L. Du.

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Wang, Q., Yan, T. & Du, L. Structure of a new three-dimensional metal-organic framework: Poly[manganese(II)-bis-(µ4-1,4-naphthalenedicarboxylate)-bis-(N,N-dimethylformamide)]. Crystallogr. Rep. 60, 869–873 (2015). https://doi.org/10.1134/S1063774515060371

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  • DOI: https://doi.org/10.1134/S1063774515060371

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