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Phase transitions in Cs5(HSO4)2(H2PO4)3 crystal

  • Physical Properties of Crystals
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Abstract

The symmetry (sp. gr.I \(\bar 4\)3d) and lattice parameters have been determined for the first time for Cs5(H2SO4)2(H2PO4)3 crystals in the temperature range from 172 to 390 K. The thermal and optical properties of crystals, as well as their conductivity, have been investigated at elevated temperatures. It is shown that a crystal heated to T = 365 K undergoes a phase transition with symmetry lowering to the tetragonal phase (with the parameters a = 4.965(1) Å and c = 5.016(1) Å), while at T ≈ 390 K a phase transition to the cubic phase is presumably observed. With a decrease in temperature, a phase transition without a change in symmetry occurs at T = 240 K.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia

    V. V. Grebenev, I. P. Makarova, D. A. Ksenofontov, V. A. Komornikov & E. V. Dmitricheva

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  1. V. V. Grebenev
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  2. I. P. Makarova
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  3. D. A. Ksenofontov
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  4. V. A. Komornikov
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  5. E. V. Dmitricheva
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Correspondence to V. V. Grebenev.

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Original Russian Text © V.V. Grebenev, I.P. Makarova, D.A. Ksenofontov, V.A. Komornikov, E.V. Dmitricheva, 2013, published in Kristallografiya, 2013, Vol. 58, No. 6, pp. 896–900.

On the 70th Anniversary of the Shubnikov Institute of Crystallography of the Russian Academy of Sciences

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Grebenev, V.V., Makarova, I.P., Ksenofontov, D.A. et al. Phase transitions in Cs5(HSO4)2(H2PO4)3 crystal. Crystallogr. Rep. 58, 894–898 (2013). https://doi.org/10.1134/S1063774513060138

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  • DOI: https://doi.org/10.1134/S1063774513060138

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