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Direct Determination of Pyrethroids in Aqueous Samples by a Metal Organic Framework “MIL-101(Cr)” Sorbent for Solid-Phase Extraction and Thermal Desorption Coupled with GC-FID

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Abstract

In this study, an online solid-phase extraction-thermal desorption method coupled with gas chromatography-flame ionization detection was used to extract seven pyrethroids from tap water and agricultural wastewater. For this purpose, a metal-organic framework MIL-101(Cr) was synthesized, and its applicability as a solid-phase sorbent was studied. Several effective parameters of the extraction efficiency such as the amount of sorbent, sample volume, sample pH, and thermal desorption procedure were also explored. Moreover, molecular docking was used to predict and assess the nature of pyrethroids adsorption on MIL-101(Cr). Additionally, the molecular interactions and the binding energies were studied and calculated. The analytical performance of the proposed method showed an excellent linear dynamic range (r = 0.9953–0.9997) for pyrethroids in the range of 0.5–10 μg/L and relative standard deviations less than 8.3% combined with satisfactory detection and quantification limits (below 0.20 and 0.9 µg/L, respectively). Under the optimal conditions, the method was successfully applied for the determination of pyrethroids in real samples (tap water and wastewater) with satisfactory recoveries in the range of 85.1–97.2%.

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ACKNOWLEDGMENTS

This work was supported by Chemistry and Chemical Engineering Research Center of Iran.

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Authors and Affiliations

  1. Faculty of Clean Technologies, Chemistry and Chemical Engineering Research Center of Iran, 17th Km of Tehran-Karaj Highway, Tehran, Iran

    Mahsa Torabizadeh, Kourosh Tabar-Heydar & Seyyed Hamid Ahmadi

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  1. Mahsa Torabizadeh
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  2. Kourosh Tabar-Heydar
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  3. Seyyed Hamid Ahmadi
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Correspondence to Kourosh Tabar-Heydar.

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Torabizadeh, M., Tabar-Heydar, K. & Ahmadi, S.H. Direct Determination of Pyrethroids in Aqueous Samples by a Metal Organic Framework “MIL-101(Cr)” Sorbent for Solid-Phase Extraction and Thermal Desorption Coupled with GC-FID. J Anal Chem 77, 1047–1056 (2022). https://doi.org/10.1134/S1061934822080068

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