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Enantioselective Voltammetric Sensors Based on Amino Acid Complexes of Cu(II), Co(III), and Zn(II)

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Abstract

The electrochemical and analytical characteristics of enantioselective sensors based on glassy carbon electrodes modified by chelate complexes (bis(L-phenylalaninate) copper(II), glycinato-L-phenylalaninate copper(II), tris(L-phenylalaninate) cobalt(II), bis(L-phenylalaninate) zinc) are studied. It is found that the most promising sensor for determining tryptophan enantiomers is the sensor modified by copper(II) (bis)L-phenylalaninate. In determining tryptophan enantiomers, this sensor provides a linear concentration range from 6.25 × 10–7 to 0.5 × 10–3 M for L-tryptophan and from 5 × 10–6 to 0.5 × 10–3 M for D-tryptophan. The sensor is more sensitive to L-tryptophan. The proposed sensor was used for the recognition and determination of tryptophan enantiomers in human urine and plasma samples, and also in a mixture of enantiomers. The statistical assessment of the results of determinations by the spiked–found method indicates the absence of a significant systematic error.

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Funding

This work was supported by the Russian Science Foundation, project no. 21-13-00169, https://rscf.ru/project/21-13-00169/.

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Authors and Affiliations

  1. Faculty of Chemistry, Bashkir State University, 450076, Ufa, Russia

    R. A. Zil’berg, L. R. Zagitova, I. V. Vakulin, Yu. A. Yarkaeva, Yu. B. Teres & T. V. Berestova

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  1. R. A. Zil’berg
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  2. L. R. Zagitova
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  3. I. V. Vakulin
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  4. Yu. A. Yarkaeva
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  5. Yu. B. Teres
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  6. T. V. Berestova
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Correspondence to R. A. Zil’berg.

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Translated by V. Kudrinskaya

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Zil’berg, R.A., Zagitova, L.R., Vakulin, I.V. et al. Enantioselective Voltammetric Sensors Based on Amino Acid Complexes of Cu(II), Co(III), and Zn(II). J Anal Chem 76, 1438–1448 (2021). https://doi.org/10.1134/S1061934821120145

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  • DOI: https://doi.org/10.1134/S1061934821120145

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