Abstract
The review surveys the works of staff members, students, and graduate students of the Divison of Analytical Chemistry, Department of Chemistry, Lomonosov Moscow State University on the use of microemulsions in liquid and electrokinetic chromatography. Microemulsions are used as promising extractants for the extraction of hydrophobic target substances from food, pharmaceutical, environmental, etc., samples. The possibility of the subsequent separation of microemulsions and the preconcentration of components to be determined in an organic phase was demonstrated. The approaches proposed are characterized by low detection limits; they considerably simplify a sample preparation process to shorten the total analysis time and to decrease the total number of stages, which decreases the error of determination.
Similar content being viewed by others
REFERENCES
Hoar, T.P. and Schulman, J.H., Nature, 1943, vol. 152, p. 102.
Danielsson, I. and Lindman, B., Colloids Surf., 1981, vol. 3, p. 391.
Kahlweit, M., Microemulsions, Science, 1988, vol. 240, no. 4852, p. 617.
Weder, H. and Mutsch, M., US Patent 5152923, 1992.
Sarker, D., Curr. Drug Delivery, 2005, vol. 2, p. 297.
Un-Nabi, S., Shakeel, F., Talegaonkar, S., Ali, J., Baboota, S., Ahuja, A., Khar, R.K., and Ali, M., AAPS PharmSciTech, 2007, vol. 8, no. 2, p. 12.
Shtykov, S.N., in Proc. Int. Trace Analysis Symposium’98, Tokyo, 1998, p. 173.
Shtykov, S.N., J. Anal. Chem., 2002, vol. 57, no. 10, p. 859.
Shtykov, S.N. and Goryacheva, I.Yu., Opt. Spectrosc., 1997, vol. 83, no. 4, p. 645.
Pashkova, E.B., Pirogov, A.V., Yunovidov, D.V., and Shpigun, O.A., Moscow Univ. Chem. Bull. (Engl. Transl.), 2011, vol. 66, no. 1, p. 38.
Pashkova, E.B., Pirogov, A.V., and Shpigun, O.A., Zavod. Lab.,Diagn. Mater., 2011, vol. 77, no. 1, p. 17.
Sokolova, L.S., Kostromskikh, A.A., Pirogov, A.V., and Shpigun, O.A., Razrab. Registratsiya Lek. Sredstv, 2014, no. 1, p. 140.
Sokolova, L.S., Pletnev, F.I., Kostromskikh, A.A., Pashkova, E.B., Pirogov, A.V., Popik, M.V., and Shpigun, O.A., Maslozhir. Prom-st., 2013, no. 6, p. 18.
Derbina, A.A., Pirogov, A.V., Kargin, I.D., and Shpigun, O.A., J. Anal. Chem., 2015, vol. 70, no. 10, p. 1271.
Tolmacheva, N.G., Pirogov, A.V., and Shpigun, O.A., Moscow Univ. Chem. Bull. (Engl. Transl.), 2017, vol. 72, no. 2, p. 92.
Tolmacheva, N.G., Zhang, M., Pirogov, A.V., Popik, M.V., and Shpigun, O.A., J. Anal. Chem., 2017, vol. 72, no. 6, p. 602.
Tolmacheva, N.G., Zhang, M., Pirogov, A.V., and Shpigun, O.A., Sorbtsionnye Khromatogr.Protsessy, 2017, vol. 17, no. 3, p. 358.
Kostromskikh, A.A., Pirogov, A.V., Sokolova, L.S., and Shpigun, O.A., J. Liq. Chromatogr. Relat. Technol., 2015, vol. 38, no. 6, p. 670.
Kostromskikh, A., Pirogov, A., Sokolova, L., and Shpigun, O., Curr. Chromatogr., 2015, vol. 2, no. 1, p. 32.
Derbina, A.A., Pirogov, A.V., Kargin, I.D., Popik, M.V., and Shpigun, O.A., Zavod. Lab.,Diagn. Mater., 2015, vol. 81, no. 6, p. 5.
Pirogov, A.V., Pashkova, E.B., Fedorova, I.A., and Shpigun, O.A., Sorbtsionnye Khromatogr.Protsessy, 2011, vol. 11, no. 2, p. 228.
Sokolova, L.S., Derbina, A.A., Pashkova, E.B., Pirogov, A.V., and Shpigun, O.A., Moscow Univ. Chem. Bull. (Engl. Transl.), 2015, vol. 70, no. 4, p. 175.
Pirogov, A.V., Pashkova, E.B., Popik, M.V., and Shpigun, O.A., Razrab. Registratsiya Lek. Sredstv, 2013, no. 4, p. 86.
Svidritskii, E.P., Pashkova, E.B., Pirogov, A.V., and Shpigun, O.A., J. Anal. Chem., 2010, vol. 65, no. 3, p. 287.
Pirogov, A., Sokolova, L., Sokerina, E., Tataurova, O., and Shpigun, O., J. Liq. Chromatogr. Relat. Technol., 2016, vol. 39, no. 4, p. 220.
Kargin, I.D., Sokolova, L.S., Pirogov, A.V., and Shpigun, O.A., Razrab. Registratsiya Lek. Sredstv, 2013, no. 4, p. 116.
Kargin, I.D., Sokolova, L.S., Pirogov, A.V., and Shpigun, O.A., Zavod. Lab.,Diagn. Mater., 2015, vol. 81, no. 2, p. 5.
Levkina, V.V., Petruk, E.S., Popik, M.V., Pirogov, A.V., and Shpigun, O.A., Moscow Univ. Chem. Bull. (Engl. Transl.), 2017, vol. 72, no. 6, p. 303.
Funding
Studies on the determination of maltenes in oils after microemulsion extraction and on the determination of PAHs were supported by the Russian Science Foundation (project no. 16-13-10079).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by V. Makhlyarchuk
Rights and permissions
About this article
Cite this article
Pirogov, A.V., Shpigun, O.A. Application of Microemulsions in Liquid Chromatography and Electrokinetic Methods of Analysis: Advantages and Disadvantages of the Approach. J Anal Chem 75, 139–147 (2020). https://doi.org/10.1134/S1061934820020148
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934820020148