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Carbonate-Selective Electrodes Based on Higher Quaternary Ammonium Salts with Increased Steric Accessibility of the Exchange Site

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Abstract

A film polyvinyl chloride (33 wt %) carbonate-selective electrode based on a higher quaternary ammonium salt with increased steric accessibility of the exchange site, 3,4,5-tris(dodecyloxy)benzyl( oxyethyl)3trimethylammonium chloride (5 wt %), was developed using o-nitrophenyl decyl ether (52 wt %) as a plasticizer and heptyl p-trifluoroacetylbenzoate (10 wt %) as a solvating agent. The limit of detection of hydrocarbonate was 1.9 × 10−9 M, lifetime was 2.5 months, and the slope of the electrode function was 32.3 ± 0.6 mV/decade. The electrode is selective in the presence of interfering SO42-, Cl−, C2O42-, Br−, HPO42-, and NO3- ions, which allows its application for the determination of HCO3- ions in mineral water.

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Authors and Affiliations

  1. Faculty of Chemistry, Belarusian State University, Minsk, 220030, Belarus

    Yu. V. Matveichuk, E. M. Rakhman’ko & E. B. Okaev

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  1. Yu. V. Matveichuk
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  2. E. M. Rakhman’ko
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  3. E. B. Okaev
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Correspondence to Yu. V. Matveichuk.

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Original Russian Text © Yu.V. Matveichuk, E.M. Rakhman’ko, E.B. Okaev, 2018, published in Zhurnal Analiticheskoi Khimii, 2018, Vol. 73, No. 7, pp. 536–544.

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Matveichuk, Y.V., Rakhman’ko, E.M. & Okaev, E.B. Carbonate-Selective Electrodes Based on Higher Quaternary Ammonium Salts with Increased Steric Accessibility of the Exchange Site. J Anal Chem 73, 719–727 (2018). https://doi.org/10.1134/S1061934818030097

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  • DOI: https://doi.org/10.1134/S1061934818030097

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