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Extraction of Metals in a Water‒Potassium Bis(Alkylpolyoxyethylene)Phosphate‒Ammonium Sulfate System with Various Photometric Reagents

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Abstract

The interfacial distribution of a number of organic photometric reagents in a water‒potassium bis(alkylpolyoxyethylene)phosphate (oxyphos B)‒ammonium sulphate splitting system is studied. It is found that alizarin complexone, 1-(2-pyridylazo)-2-naphthol-2 (PAN), bromothymol blue, rhodamine 6G, pyrogallol red, morin, fuchsine, malachite green, bromothymol blue, pyrocatechol violet (PCV), chromazurol S, and aluminon are extracted with partition coefficients higher than 100. A possibility of the extraction‒photometric determination of gallium with PCV and cobalt with PAN is shown. The proposed procedures do not require the use of fire-hazardous, volatile, and toxic organic solvents.

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Authors and Affiliations

  1. Department of Chemistry, Perm State University, Perm’, 614990, Russia

    S. A. Denisova

  2. Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm’, 614013, Russia

    A. E. Lesnov & N. N. Ostanina

  3. Department of Agrochemistry, Perm State Agricultural Academy, Perm’, 614000, Russia

    A. E. Lesnov

Authors
  1. S. A. Denisova
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  2. A. E. Lesnov
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  3. N. N. Ostanina
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Correspondence to A. E. Lesnov.

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Original Russian Text © S.A. Denisova, A.E. Lesnov, N.N. Ostanina, 2018, published in Zhurnal Analiticheskoi Khimii, 2018, Vol. 73, No. 5, pp. 352–357.

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Denisova, S.A., Lesnov, A.E. & Ostanina, N.N. Extraction of Metals in a Water‒Potassium Bis(Alkylpolyoxyethylene)Phosphate‒Ammonium Sulfate System with Various Photometric Reagents. J Anal Chem 73, 427–431 (2018). https://doi.org/10.1134/S1061934818030048

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  • DOI: https://doi.org/10.1134/S1061934818030048

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