Abstract
We studied the capabilities of different versions of the on-line preconcentration of steroid hormones (field-amplifying sample stacking, sweeping, sweeping in high-salt sample matrix) in micellar electrokinetic chromatography using an ionic liquid (IL) of 3-methyl-1-cetylimidazolium chloride (C16MImCl) as a component of a background electrolyte. The optimal conditions for the preconcentration of hormones are found. The simultaneous addition of the above ionic liquid (0.5 mM) and sodium dodecyl sulfate (25 mM) to the background electrolyte ensures efficiency of up to ∼1 × 106 theoretical plates and detection limits for hormones down to 25–100 ng/mL.
Similar content being viewed by others
References
Sun, P. and Armstrong, D.W., Anal. Chim. Acta, 2010, vol. 661, p. 1.
Berthod, A., Ruiz-A’ngel, M.J., and Carda-Broch, S., J. Chromatogr. A, 2008, vol. 1184, p. 6.
Soukup-Hein, R.J., Warnke, M.M., and Armstrong, D.W., Annu. Rev. Anal. Chem., 2009, vol. 2, p. 145.
Pino, V., German-Hernandez, M., Martin-Perez, A., and Anderson, J.L., Sep. Sci. Technol., 2012, vol. 47, p. 264.
Bowers, J., Butts, C.P., Martin, P.J., and Vergara- Gutierrez, M.C., Langmuir, 2004, vol. 20, p. 2191.
Baker, G.A., Pandey, S., Pandey, S., and Baker, S.N., Analyst, 2004, vol. 129, p. 890.
Dong, B., Zhao, X., Zheng, L., Zhang, J., Li, N., and Inoue, T., Colloids Surf., A, 2008, vol. 317, p. 666.
Quirino, J.P., Anres, P., Sirieix-Plenet, J., Delaunay, N., and Gareil, P., J. Chromatogr. A, 2011, vol. 1218, p. 5718.
Wang, Q., Qiu, H., Han, H., Liu, X., and Jiang, S., J. Sep. Sci, 2012, vol. 35, p. 589.
Rageh, A.H. and Pyell, U., J. Chromatogr. A, 2013, vol. 1316, p. 135.
Abd El-Hady, D. and Albishri, H.M., J. Chromatogr. B: Anal. Technol. Biomed. Life Sci., 2014, vol. 969, p. 224.
Su, H.-L., Lan, M.-T., and Hsieh, Y.-Z., J. Chromatogr. A, 2009, vol. 1216, p. 5313.
Abd El-Hady, D., Albishri, H.M., Rengarajan, R., and Watzig, H., Electrophoresis, 2014, vol. 35, p. 1956.
Breadmore, M.C., Shallan, A.I., Rabanes, H.R., Gstoettenmayr, D., Abdul-Keyon, A.S., Gaspar, A., Dawod, M., and Quirino, J.P., Electrophoresis, 2013, vol. 34, p. 29.
Francois, Y., Varenne, A., Juillerat, E., and Gareil, P., J. Chromatogr. A, 2007, vol. 1155, p. 134.
Su, H., Lan, M., and Hsieh, Y., J. Chromatogr. A, 2009, vol. 1216, p. 5313.
Schnee, V.P., Baker, G.A., Rauk, E., and Palmer, C.P., Electrophoresis, 2006, vol. 27, p. 41.
Pino, V., German-Hemandez, M., Martin-Perez, A., and Anderson, J.L., Sep. Sci. Technol., 2012, vol. 47, p. 264.
Kitagawa, F. and Otsuka, K., J. Chromatogr. A, 2014, vol. 1335, p. 43.
Quirino, J.P. and Terabe, S., Science, 1998, vol. 282, p. 465.
Quirino, J.P., Kim, J.-B., and Terabe, S., J. Chromatogr. A, 2002, vol. 965, p. 357.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.A. Bessonova, L.A. Kartsova, V.F. Gallyamova, 2016, published in Zhurnal Analiticheskoi Khimii, 2016, Vol. 71, No. 7, pp. 724–730.
Rights and permissions
About this article
Cite this article
Bessonova, E.A., Kartsova, L.A. & Gallyamova, V.F. Effect of 3-methyl-1-cetylimidazolium chloride ionic liquid on the electrophoretic preconcentration of steroid hormones. J Anal Chem 71, 696–702 (2016). https://doi.org/10.1134/S1061934816070042
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934816070042