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High-performance liquid chromatography–time-of-flight mass spectrometry in the identification and determination of 111 pesticides in food, feed, water, and soil

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Abstract

A method has been proposed for the simultaneous identification and determination of 111 pesticides from various classes in food by high-performance liquid chromatography–high-resolution time-offlight mass spectrometry combined with simple and fast sample preparation. Possibility of the identification and determination of pesticides in drinking, natural, and ground waters without sample preparation has been demonstrated. A scheme of the identification and determination of the detected analytes using the standard addition method has been suggested. The limit of detection is 0.05 (0.1) µg/(L)kg. The relative standard deviation of the results of analysis does not exceed 0.1. The time of identification is 30–40 min and time of determination is 1–2 h.

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Authors and Affiliations

  1. Federal Center for Animals Health, Yur’evets, Vladimir, 600901, Russia

    V. G. Amelin

  2. Vladimir State University, ul. Gor’kogo 87, Vladimir, 600000, Russia

    V. G. Amelin & A. M. Andoralov

  3. Bryansk Interregional Veterinary Laboratory, ul. Shosseinaya 7, Suponevo, Bryank oblast, 241520, Russia

    A. M. Andoralov

Authors
  1. V. G. Amelin
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  2. A. M. Andoralov
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Correspondence to V. G. Amelin.

Additional information

Original Russian Text © V.G. Amelin, A.M. Andoralov, 2016, published in Zhurnal Analiticheskoi Khimii, 2016, Vol. 71, No. 1, pp. 85–96.

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Amelin, V.G., Andoralov, A.M. High-performance liquid chromatography–time-of-flight mass spectrometry in the identification and determination of 111 pesticides in food, feed, water, and soil. J Anal Chem 71, 82–93 (2016). https://doi.org/10.1134/S1061934815120035

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  • DOI: https://doi.org/10.1134/S1061934815120035

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