Skip to main content
Log in

Study of the processes of background formation in the long-wavelength region of X-Ray spectrum

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Using mathematical design of experiments we studied the spectral composition of an X-ray background in the wavelength region 0.3–1.2 nm in the X-ray fluorescence analysis (XRF) of samples with matrices composed of elements with small atomic numbers, viz plant materials. The interpretation of the results allowed us to quantitatively estimate components of X-ray background for spectrometers with wavelength dispersion and to reveal their dependence on the chemical composition of the specimens. Recommendations are formulated for the account of the background in the plant XRF.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Blokhin, M.A. and Druz’, V.V., Abstracts of Papers, VIII Soveshch. po rentgenovskoi spektroskopii (VIII Meeting on X-Ray Spectroscopy), Apatity, 1966, p. 98.

    Google Scholar 

  2. Revenko, A.G., Pavlinskii, G.V., Losev, N.F., and Afonin, V.P., Zavod. Lab., 1970, vol. 36, no. 2, p. 166.

    CAS  Google Scholar 

  3. Revenko, A.G., Pavlinskii, G.V., and Losev, N.F., Zavod. Lab., 1974, vol. 40, no. 11, p. 1334.

    CAS  Google Scholar 

  4. Sukhorukov, B.L., Smagunova, A.N., Pavlinskii, G.V., and Losev, N.F., Zh. Anal. Khim., 1975, vol. 30, no. 2, p. 372.

    CAS  Google Scholar 

  5. Losev, N.F. and Smagunova, A.N., Osnovy rentgenospe-ktral’nogo fluorestsentnogo analiza (Fundamentals of X-Ray Fluorescence Analysis), Moscow: Khimiya, 1982.

    Google Scholar 

  6. Lozhkin, V.I. and Afonin, V.P., Zavod. Lab., 1976, vol. 42, no. 9, p. 1075.

    Google Scholar 

  7. Pavlinskii, G.V., Ivshev, D.V., and Imeshkenova, N.N., Zh. Anal. Khim., 1991, vol. 46, no. 3, p. 525.

    CAS  Google Scholar 

  8. Nielson, K.K., X-ray Spectrom., 1978, vol. 7, no. 1, p. 15.

    Article  CAS  Google Scholar 

  9. Rachetti, A. and Wegscheider, W., Adv. X-ray Anal., 1987, vol. 30, p. 143.

    CAS  Google Scholar 

  10. Smagunova, A.N., Molchanova, E.I., and Usova, E.R., Zh. Anal. Khim., 1987, vol. 42, no. 10, p. 1797.

    CAS  Google Scholar 

  11. Bazykina, E.N., Smagunova, A.N., and Baranova, O.A., Zh. Anal. Khim., 1984, vol. 34, no. 10, p. 1745.

    Google Scholar 

  12. Queralt, I., Ovejero, M., Carvalho, M.L., Marques, A.F., and Llabres, J.M., X-ray Spectrom., 2005, vol. 34, no. 3, p. 213.

    Article  CAS  Google Scholar 

  13. Guohui Li and Shouzhong Fan, J. Geochem. Explor., 1995, vol. 55, p. 75.

    Article  CAS  Google Scholar 

  14. Lopes de Ruiz, R.E., Olsina, R.A., and Masi, A.N., X-ray Spectrom., 2002, vol. 31, no. 2, p. 150.

    Article  Google Scholar 

  15. Jánošová, V., Sy'korová, M., Štroffeková, O., and Havránek, E., J. Anal. Chem., 2010, vol. 65, no. 1, p. 56.

    Article  Google Scholar 

  16. Adler, Yu.P., Markova, E.V., and Granovskii, Yu.A., Planirovanie eksperimenta pri poiske optimal’nykh uslovii (Planning Experiment in Finding the Optimal Conditions), Moscow: Nauka, 1971.

    Google Scholar 

  17. Hoenig, M., Baeten, H., Vanhentenrijk, S., Vassileva, E., and Quevauviller, Ph., Anal. Chim. Acta, 1998, vol. 358, no. 1, p. 85.

    Article  CAS  Google Scholar 

  18. Chuparina, E.V. and Gunicheva, T.N., J. Anal. Chem., 2003, vol. 58, no. 9, p. 856.

    Article  CAS  Google Scholar 

  19. Smagunova, A.N. and Karpukova, O.M., Metody matematicheskoi statistiki v analiticheskoi khimii: ucheb. posobie (Statistical Methods in Analytical Chemistry: A Textbook), Rostov-on-Don: Feniks, 2012.

    Google Scholar 

  20. Hubbell, J.H. and Seltzer, S.M., Tables of X-ray Mass Attenuation Coefficients and Mass Energy-Absorption Coefficients from 1 keV to 20 meV for Elements Z = 1 to 92 and 48 Additional Substances of Dosimetric Interest. http://www.nist.gov/pml/data/xraycoef/index.cfm. Accessed April 23, 2014.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. V. Chuparina.

Additional information

Original Russian Text © E.V. Chuparina, A.N. Smagunova, L.A. Eliseeva, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 8, pp. 828–834.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chuparina, E.V., Smagunova, A.N. & Eliseeva, L.A. Study of the processes of background formation in the long-wavelength region of X-Ray spectrum. J Anal Chem 70, 949–955 (2015). https://doi.org/10.1134/S1061934815080055

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934815080055

Keywords

Navigation