Abstract
Using mathematical design of experiments we studied the spectral composition of an X-ray background in the wavelength region 0.3–1.2 nm in the X-ray fluorescence analysis (XRF) of samples with matrices composed of elements with small atomic numbers, viz plant materials. The interpretation of the results allowed us to quantitatively estimate components of X-ray background for spectrometers with wavelength dispersion and to reveal their dependence on the chemical composition of the specimens. Recommendations are formulated for the account of the background in the plant XRF.
Similar content being viewed by others
References
Blokhin, M.A. and Druz’, V.V., Abstracts of Papers, VIII Soveshch. po rentgenovskoi spektroskopii (VIII Meeting on X-Ray Spectroscopy), Apatity, 1966, p. 98.
Revenko, A.G., Pavlinskii, G.V., Losev, N.F., and Afonin, V.P., Zavod. Lab., 1970, vol. 36, no. 2, p. 166.
Revenko, A.G., Pavlinskii, G.V., and Losev, N.F., Zavod. Lab., 1974, vol. 40, no. 11, p. 1334.
Sukhorukov, B.L., Smagunova, A.N., Pavlinskii, G.V., and Losev, N.F., Zh. Anal. Khim., 1975, vol. 30, no. 2, p. 372.
Losev, N.F. and Smagunova, A.N., Osnovy rentgenospe-ktral’nogo fluorestsentnogo analiza (Fundamentals of X-Ray Fluorescence Analysis), Moscow: Khimiya, 1982.
Lozhkin, V.I. and Afonin, V.P., Zavod. Lab., 1976, vol. 42, no. 9, p. 1075.
Pavlinskii, G.V., Ivshev, D.V., and Imeshkenova, N.N., Zh. Anal. Khim., 1991, vol. 46, no. 3, p. 525.
Nielson, K.K., X-ray Spectrom., 1978, vol. 7, no. 1, p. 15.
Rachetti, A. and Wegscheider, W., Adv. X-ray Anal., 1987, vol. 30, p. 143.
Smagunova, A.N., Molchanova, E.I., and Usova, E.R., Zh. Anal. Khim., 1987, vol. 42, no. 10, p. 1797.
Bazykina, E.N., Smagunova, A.N., and Baranova, O.A., Zh. Anal. Khim., 1984, vol. 34, no. 10, p. 1745.
Queralt, I., Ovejero, M., Carvalho, M.L., Marques, A.F., and Llabres, J.M., X-ray Spectrom., 2005, vol. 34, no. 3, p. 213.
Guohui Li and Shouzhong Fan, J. Geochem. Explor., 1995, vol. 55, p. 75.
Lopes de Ruiz, R.E., Olsina, R.A., and Masi, A.N., X-ray Spectrom., 2002, vol. 31, no. 2, p. 150.
Jánošová, V., Sy'korová, M., Štroffeková, O., and Havránek, E., J. Anal. Chem., 2010, vol. 65, no. 1, p. 56.
Adler, Yu.P., Markova, E.V., and Granovskii, Yu.A., Planirovanie eksperimenta pri poiske optimal’nykh uslovii (Planning Experiment in Finding the Optimal Conditions), Moscow: Nauka, 1971.
Hoenig, M., Baeten, H., Vanhentenrijk, S., Vassileva, E., and Quevauviller, Ph., Anal. Chim. Acta, 1998, vol. 358, no. 1, p. 85.
Chuparina, E.V. and Gunicheva, T.N., J. Anal. Chem., 2003, vol. 58, no. 9, p. 856.
Smagunova, A.N. and Karpukova, O.M., Metody matematicheskoi statistiki v analiticheskoi khimii: ucheb. posobie (Statistical Methods in Analytical Chemistry: A Textbook), Rostov-on-Don: Feniks, 2012.
Hubbell, J.H. and Seltzer, S.M., Tables of X-ray Mass Attenuation Coefficients and Mass Energy-Absorption Coefficients from 1 keV to 20 meV for Elements Z = 1 to 92 and 48 Additional Substances of Dosimetric Interest. http://www.nist.gov/pml/data/xraycoef/index.cfm. Accessed April 23, 2014.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.V. Chuparina, A.N. Smagunova, L.A. Eliseeva, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 8, pp. 828–834.
Rights and permissions
About this article
Cite this article
Chuparina, E.V., Smagunova, A.N. & Eliseeva, L.A. Study of the processes of background formation in the long-wavelength region of X-Ray spectrum. J Anal Chem 70, 949–955 (2015). https://doi.org/10.1134/S1061934815080055
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934815080055