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Planar electrodes based on carbon nanotubes for the potentiometric determination of homologous sodium alkyl sulfates

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Abstract

Planar electrodes based on carbon nanotubes, manufactured by screen printing, are proposed for the determination of anionic surfactants in aqueous solutions. A comparative analysis of the electroanalytical characteristics of planar and solid-state sensors based on various ionophores, namely, ion associates of (1) sodium dodecyl sulfate with a cationic complexes of copper(II) and N,N′-bis(salicylidene)ethylenediamine and (2) sodium dodecyl sulfate with cetylpyridinium, is performed. It is shown that planar electrodes can be used to quantify homologous sodium alkyl sulfates in the concentrations range of 4 × 10−7 (5 × 10−6) to 1 × 10−2 (5 × 10−4) M at pH 4–10 in water bodies and to determine the total concentration of anionic surfactants in detergents.

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Authors and Affiliations

  1. Chernyshevskii State University, Saratov, Astrakhanskaya ul. 83, Saratov, 410012, Russia

    N. M. Makarova & E. G. Kulapina

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  1. N. M. Makarova
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  2. E. G. Kulapina
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Correspondence to N. M. Makarova.

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Original Russian Text © N.M. Makarova, E.G. Kulapina, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 7, pp. 764–769.

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Makarova, N.M., Kulapina, E.G. Planar electrodes based on carbon nanotubes for the potentiometric determination of homologous sodium alkyl sulfates. J Anal Chem 70, 879–884 (2015). https://doi.org/10.1134/S1061934815070096

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  • DOI: https://doi.org/10.1134/S1061934815070096

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