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Chemical differentiation of silver(I), gold(I), and palladium(II) complexes with dipropyl disulfide groups covalently bound to a silica surface and Michler’s thioketone in solid-phase spectrophotometry

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Abstract

A method is proposed for the adsorption-photometric determination of silver, gold, and palladium from one sample as their mixed-ligand complexes with dipropyl disulfide groups covalently bound to a silica surface and Michler’s thioketone, based on the measurement of the intensity of the adsorbent color, decreasing after treatment with destructive agents. The method is used for the determination of gold and palladium in the copper-nickel sludge.

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Authors and Affiliations

  1. Kristall Research and Engineering Center, Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, 660041, Russia

    V. N. Losev, O. V. Buiko & E. V. Borodina

  2. Faculty of Chemistry, Taras Shevchenko National University, Kyiv, ul. Vladimirskaya 64, Kyiv, 01033, Ukraine

    A. K. Trofimchuk

Authors
  1. V. N. Losev
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  2. O. V. Buiko
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  3. E. V. Borodina
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  4. A. K. Trofimchuk
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Correspondence to V. N. Losev.

Additional information

Original Russian Text © V.N. Losev, O.V. Buiko, E.V. Borodina, A.K. Trofimchuk, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 4, pp. 365–369.

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Losev, V.N., Buiko, O.V., Borodina, E.V. et al. Chemical differentiation of silver(I), gold(I), and palladium(II) complexes with dipropyl disulfide groups covalently bound to a silica surface and Michler’s thioketone in solid-phase spectrophotometry. J Anal Chem 70, 431–435 (2015). https://doi.org/10.1134/S1061934815040085

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  • DOI: https://doi.org/10.1134/S1061934815040085

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