Skip to main content
SpringerLink
Log in

Photometric redox determination of iodate ions in bottled drinking water

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A photometric procedure is proposed for the highly selective determination of iodate ions in bottled natural drinking water treated with ozone. The procedure is based on the oxidation of Methylene Blue or Variamine Blue by iodate ions. The detection limits for iodates obtained with these reagents are 0.2 and 0.4 μg/L, respectively. In determining iodate ions with Methylene Blue, the permissible weight ratios of related ion are 1: 60 for BrO3 − and NO2 −; 1: 100 for ClO− and ClO2 −; and 1: 200 for ClO3 −, ClO4 −, IO4 −, I−, and Br−. In the case of Variamine Blue, the ratios of related ion are 1: 10 for BrO3 − and NO2 −; 1: 20 for ClO− and ClO2 −; and 1: 100 for ClO3 −, ClO4 −, IO4 −, I−, and Br−. In the concentration range of iodates of 1–10 μg/L, the total error of determination is 5–7%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Korzh, V.D., Geokhimiya elementnogo sostava gidrosfery (Geochemistry of the Elemental Composition of the Hydrosphere), Moscow: Nauka, 1991.

    Google Scholar 

  2. Hypochlorite: an assessment of factors that influence the formation of perchlorate and other contaminants, American Works Association, 2009.

  3. Von Gunten, U., Water Res., 2003, vol. 37, no. 7, p. 1469.

    Article  Google Scholar 

  4. Snyder, S.A., Vanderford, B.J., and Rexing, D.J., Environ. Sci. Technol., 2005, vol. 39, no. 12, p. 4586.

    Article  CAS  Google Scholar 

  5. Burgi, H., Schaffner, T., and Seiler, J.P., Thyroid, 2001, vol. 11, no. 5, p. 449.

    Article  CAS  Google Scholar 

  6. Barron, L. and Paull, B., Talanta, 2006, vol. 69, no. 3, p. 621.

    Article  CAS  Google Scholar 

  7. Liu, Y., Mou, S., and Heberling, S., J. Chromatogr. A, 2002, vol. 956, nos. 1–2, p. 85.

    Article  CAS  Google Scholar 

  8. Binghui, Z., Zhixiong, Z., and Jing, Y., J. Chromatogr. A, 2006, vol. 1118, no. 1, p. 106.

    Article  Google Scholar 

  9. Bichsel, Y. and von Gunten, U., Anal. Chem., 1999, vol. 71, no. 1, p. 34.

    Article  CAS  Google Scholar 

  10. Weinberg, H.S. and Yamada, H., Anal. Chem., 1998, vol. 70, no. 1, p. 1.

    Article  CAS  Google Scholar 

  11. Eickhorst, T. and Seubert, A., J. Chromatogr. A, 2004, vol. 1050, no. 1, p. 103.

    Article  CAS  Google Scholar 

  12. Charles, L. and Pepin, D., Anal. Chem., 1998, vol. 70, no. 2, p. 353.

    Article  CAS  Google Scholar 

  13. Marczenko, Z. and Balcerzak, M., Separation, Preconcentration, and Spectrophotometry in Inorganic Analysis, Amsterdam: Elsevier, 2001.

    Google Scholar 

  14. Benvidi, A., Heidari, F., Tabarak, R., and MazloumArdakani, M., J. Anal. Chem., 2012, vol. 67, no. 7, p. 661.

    Article  CAS  Google Scholar 

  15. Zarei, A.R., J. Anal. Chem., 2009, vol. 64, no. 9, p. 896.

    Article  CAS  Google Scholar 

  16. Barzegar, M., Khajehsharifi, H., and Mousavi, M.F., Can. J. Anal. Sci. Spectrosc., 2003, vol. 48, no. 5, p. 303.

    CAS  Google Scholar 

  17. Liang, A.H., Jiang, Z.L., Zhang, B.M., Liu, Q.Y., Lan, J., and Lu, X., Anal. Chim. Acta, 2005, vol. 530, no. 1, p. 131.

    Article  CAS  Google Scholar 

  18. Elipasheva, E.V., Nayanova, E.V., Kulikov, P.N., Sergeev, G.M., and Sergeeva, V.P., Analitika kontrol’, 2012, vol. 16, no. 1, p. 75.

    Google Scholar 

  19. Nayanova, E.V., Sergeev, G.M., Elipasheva, E.V., and Kulikov, P.N., Voda: khim. ekol., 2013, no. 5, p. 87.

    Google Scholar 

  20. Tur’yan, Ya.I., Okislitel’no-vosstanovitel’nye reaktsii i potentsialy v analiticheskoi khimii (Redox Reactions and Potentials in Analytical Chemistry), Moscow: Khimiya, 1989.

    Google Scholar 

  21. Singhal, G.S. and Rabinowitch, E., J. Phys. Chem., 1967, vol. 71, no. 10, p. 3347.

    Article  CAS  Google Scholar 

  22. Sreevidya, T.V. and Narayana, B., Eurasian J. Anal. Chem., 2009, vol. 4, no. 1, p. 119.

    Google Scholar 

  23. Burykina, O.V., Mal’tseva, V.S., Shevlyakova, O.A., and Duplikhina, M.G., RF Patent 2377557, 2009. http://www.freepatent.ru/patents/2377557. Cited January 30, 2014.

  24. Eksperiandova, L.P., Belikov, K.N., Khimchenko, S.V., and Blank, T.A., J. Anal. Chem., 2010, vol. 65, no. 3, p. 223.

    Article  CAS  Google Scholar 

  25. Doerffel, K., Statistik in der analytischen Chemie (Statistics in Analytical Chemistry), Leipzig: Grundstoffindustrie, 1990, 5 ed.

    Google Scholar 

  26. Dvorkin, V.I., Metrologiya i obespechenie kachestva kolichestvennogo khimicheskogo analiza (Metrology and Quality Control of Quantitative Chemical Analysis), Moscow: Khimiya, 2001.

    Google Scholar 

  27. EPA-821-B-04-005: Revised Assessment of Detection and Quantitation Appoaches, 2004. http://www.epa.gov./waterscience/method/det/rad.pdf. Cited January 30, 2014.

  28. Ghasemi, J.B. and Milodi, M., J. Chin. Chem. Soc., 2009, vol. 56, no. 3, p. 459.

    CAS  Google Scholar 

  29. Bergmann, K. and O’Koski, C.T., J. Phys. Chem., 1963, vol. 67, no. 10, p. 2169.

    Article  CAS  Google Scholar 

  30. Frumina, N.S., Teoriya i praktika primeneniya reagentov difenilaminovogo klassa v analize (Theory and Practice of Application of Diphenylamine Reagents in Analysis), Saratov: Saratovsk. univ., 1976.

    Google Scholar 

  31. Krainov, S.R., Ryzhenko, B.N., and Shvets, V.M., Geokhimiya podzemnykh vod. Teoreticheskie, prikladnye i ekologicheskie aspekty (Geochemistry of Groundwater: Theoretical, Application, and Environmental Aspects), Moscow: Nauka, 2004.

    Google Scholar 

  32. SanPiN (Sanitary Regulations) 2.1.4.1116-02: Potable Water: Hygienic Requirements for Quality of Water Packaged in Containers. Quality Control,, Moscow, 2000.

  33. Gmurman, V.E., Teoriya veroyatnostei i matematicheskaya statistika: Ucheb. posobie dlya vuzov, (Probability Theory and Mathematical Statistics: Textbook for High Schools), Moscow: Vysshaya shkola, 2003, 9th ed.

    Google Scholar 

  34. Shlyapunova, E.V. and Sergeev, G.M., Vestnik Nizhegor. Gos. Univ., 2010, no. 1, p. 116.

    Google Scholar 

  35. Kulikov, P.N., Sergeev, G.M., Elipasheva, E.V., and Nayanova, E.V., Analitika kontrol’, 2012, vol. 16, no. 4, p. 388.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Lobachevskii State University, Nizhny Novgorod, pr. Gagarina 23, Nizhny Novgorod, 603950, Russia

    E. V. Nayanova, E. V. Elipasheva & G. M. Sergeev

Authors
  1. E. V. Nayanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Elipasheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. M. Sergeev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. M. Sergeev.

Additional information

Original Russian Text © E.V. Nayanova, E.V. Elipasheva, G.M. Sergeev, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 5, pp. 497–501.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nayanova, E.V., Elipasheva, E.V. & Sergeev, G.M. Photometric redox determination of iodate ions in bottled drinking water. J Anal Chem 70, 573–577 (2015). https://doi.org/10.1134/S1061934815030144

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934815030144

Keywords

Search

Navigation