Skip to main content
Log in

Study of the acid-base properties of quercetin in aqueous solutions by color measurements

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Acid-base properties of quercetin in aqueous solutions are studied by the method chemical color measurements and dissociation constants (pK) are determined. The pK values are assigned to corresponding functional groups of quercetin and a probable scheme of their dissociation is proposed. A diagram of the distribution of ion-molecular forms of quercetin in the pH range 1–13 is built.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Larsen, L., Nielsen, J., and Sorensen, H., Phytochemistry, 1982, vol. 21, no. 5, p. 1029.

    Article  CAS  Google Scholar 

  2. Harborne, J.B., Williams, C.A., and Harborne, J.B., London, 1988, p. 303.

    Google Scholar 

  3. Rice-Evans, C. and Parker, L., Flavonoids in Health and Diseases, New York: Dekker, 1998.

    Google Scholar 

  4. Magnani, L., Gaydou, E., and Hubaud, J., Anal. Chim. Acta, 2000, vol. 411, nos. 1–2, p. 209.

    Article  CAS  Google Scholar 

  5. Shorina, N.V., Kosyakov, D.S., and Bogolitsyn, K.G., Zh. Prikl. Khim., 2005, vol. 78, no. 1, p. 27.

    Google Scholar 

  6. Roginskii, V.A., Fenol’nye antioksidanty (Phenol Antioxidants), Moscow: Nauka, 1988.

    Google Scholar 

  7. Grotewold, E., The Science of Flavonoids, New York: Springer, 2006.

    Book  Google Scholar 

  8. Holzbecher, Z., Davis, L., Kral, M., Sucha, L., and Vlacil, F., Handbook of Organic Reagents in Inorganic Analysis, Wiley, 1976.

    Google Scholar 

  9. Pilipenko, A.T., Volkova, O., and Get’man, T.O., Kukibaev T.U, Ukr. Khim. Zh., 1972, vol. 38, no. 9, p. 907.

    Google Scholar 

  10. Aprelkova, N.F., Matveev, D.A., Arbuzova, E.A., Karachun, T.V., and Kraikivskii, P.B., Khim. Rastit. Syr’ya, 2010, no. 4, p. 83.

    Google Scholar 

  11. Zenkevich, I.G. and Guschina, S.V., J. Anal. Chem., 2010, vol. 65, no. 4, p. 371.

    Article  CAS  Google Scholar 

  12. Bila, N.I., Bilyj, O.V., Pron’ko, L.M., and Popov, O.A., Vestn. Donetsk Univ., A, 2012, no. 2, p. 110.

    Google Scholar 

  13. Herrero-Martinez, J., Repolles, C., Bosch, E., Roses, M., and Rafols, C., Talanta, 2008, vol. 74, no. 4, p. 1008.

    Article  CAS  Google Scholar 

  14. Momić T., Savić J., Cernigoj U., Trebse P., Vasić, V., Collect. Czech. Chem. Commun., 2007, vol. 72, no. 11, p. 1447.

    Article  Google Scholar 

  15. Sanmartin, M., Roses, M., Bosch, E., and Rafols, C., Electrophoresis, 2005, vol. 26, no. 10, p. 1886.

    Article  Google Scholar 

  16. Prasad, K., Raheem, S., Vijayaleksmi, P., and Sastri, C., Talanta, 1996, vol. 43, no. 8, p. 1187.

    Article  CAS  Google Scholar 

  17. Ivanov, V.M. and Kuznetsova, O.V., Usp. Khim., 2001, vol. 70, no. 5, p. 411.

    Article  Google Scholar 

  18. Ivanov, V.M., Adamova, E.M., and Figurovskaya, V.N., J. Anal. Chem., 2010, vol. 65, no. 5, p. 473.

    Article  CAS  Google Scholar 

  19. Chebotar’ov, O.M., Efimova, I.S., Borisyuk, N.A., and Snigur D.V., Metody i ob“ekty khim. analiza, 2011, vol. 6, no. 4, p. 207.

    Google Scholar 

  20. Chebotarev, A.N., Snigur, D.V., Guzenko, E.M., Efimova, I.S., and Shcherbakova, T.M., Vestn. Odess. Univ., Ser. Khim., 2012, vol. 16, no. 4, p. 28.

    Google Scholar 

  21. Laitinen, H.A. and Harris, W.E., Chemical Analysis, New York: McGraw-Hill, 1975.

    Google Scholar 

  22. Sovin, O.R. and Patsai I.O, Metody i ob“ekty khim. analiza, 2012, vol. 7, no. 2, p. 74.

    Google Scholar 

  23. Kunal, Poy., Paul, L., and Popeliel, A., J. Phys. Org. Chem., 2009, vol. 22, no. 3, p. 186.

    Article  Google Scholar 

  24. Zenkevich, I.G., Eshchenko, A.Yu., Makarova, S.V., Vitenberg, A.G., Dobryakov, Yu.G., and Utsal, V.A., Molecules, 2007, vol. 12, no. 3, p. 654.

    Article  CAS  Google Scholar 

  25. Vershinin, V.I and Pertsev, N.V., Planirovanie i matematicheskaya obrabotka rezul’tatov khimicheskogo eksperimenta (Design and Mathematical Processing of the Results of Chemical Experiment), Omsk: Omsk Univ., 2005.-2005.

    Google Scholar 

  26. Jurd, L., Phytochemistry, 1969, vol. 8, no. 2, p. 445.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. N. Chebotarev.

Additional information

Original Russian Text © A.N. Chebotarev, D.V. Snigur, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 1, pp. 53–57.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chebotarev, A.N., Snigur, D.V. Study of the acid-base properties of quercetin in aqueous solutions by color measurements. J Anal Chem 70, 55–59 (2015). https://doi.org/10.1134/S1061934815010062

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934815010062

Keywords

Navigation