Abstract
Relative linear adsorption-induced deformation of granules of AR-V microporous carbon adsorbent has been measured upon n-octane adsorption at pressures p of 1 Pa to 1.6 kPa and temperatures T = 273, 293, 313, 353, and 393 K. At p > 200 Pa, the adsorption-induced deformation is positive and grows with p throughout the considered temperature range. Under isobaric conditions, the adsorption-induced deformation and the slope of deformation isotherms increase as T decreases. At p < 200 Pa and T < 350 K, the adsorption-induced deformation is negative. The range of adsorbent contraction narrows with an increase in T, and, at T > 350 K, the adsorbent expands throughout the pressure range. Molecular dynamics simulation has been employed to study the structure of n-octane adsorption associates in model slit-like micropores having a width corresponding to the effective size of micropores in AR-V adsorbent calculated in terms of the theory of volume filling of micropores. The structure of the adsorption associates has been related to the characteristic features of the adsorption-induced deformation of AR-V adsorbent.
Similar content being viewed by others
REFERENCES
Rehbinder, P.A., Usp. Fiz. Nauk, 1972, vol. 108, p. 3.
Rusanov, A.I., Dokl. Phys. Chem., 2006, vol. 406, p. 49.
Rusanov, A.I., Termodinamicheskie osnovy mekhanokhimii (Thermodynamic Fundamentals of Mechanochemistry), St. Petersburg: Nauka, 2006.
Rusanov, A.I., Colloid J., 2007, vol. 69, p. 807.
Fomkin, A.A., Shkolin, A.V., Pulin, A.L., Men’shchikov, I.E., and Khozina, E.V., Colloid J., 2018, vol. 80, p. 578.
Shkolin, A.V., Potapov, S.V., and Fomkin, A.A., Colloid J., 2015, vol. 77, p. 812.
Potapov, S.V., Shkolin, A.V., and Fomkin, A.A., Colloid J., 2014, vol. 76, p. 351.
Shkolin, A.V. and Fomkin, A.A., Colloid J., 2009, vol. 71, p. 119.
Balzer, C., Wildhage, T., Braxmeier, S., Reichenauer, G., and Olivier, J.P., Langmuir, 2011, vol. 27, p. 2553.
Yakovlev, V.Yu., Fomkin, A.A., and Tvardovski, A.V., J. Colloid Interface Sci., 2004, vol. 280, p. 305.
Shkolin, A.V. and Fomkin, A.A., Protection of Metals and Physical Chemistry of Surfaces, 2013, vol. 49, no. 4, p. 373.
Shkolin, A.V., Fomkin, A.A., and Sinitsyn, V.A., Protection of Metals and Physical Chemistry of Surfaces, 2011, vol. 47, no. 5, p. 555.
Yakovlev, V.Y., Fomkin, A.A., and Tvardovski, A.V., J. Colloid Interface Sci., 2003, vol. 268, p. 33.
Fomkin, A.A., Adsorption, 2005, vol. 11, p. 425.
Fomkin, A.A. and Shkolin, A.V., Dokl. Phys. Chem., 2008, vol. 423, p. 292.
Fomkin, A.A., Shkolin, A.V., and Petukhova, G.A., Protection of Metals and Physical Chemistry of Surfaces, 2012, vol. 48, no. 2, p. 158.
Fenelonov, V.B., Poristyi uglerod (Porous Carbon), Novosibirsk: IK SO RAN, 1995.
Dubinin, M.M., Adsorbtsiya i poristost’ (Adsorption and Porosity), Moscow: VAKhZ, 1972.
Eksperimental’nye metody v adsorbtsii i khromatografii (Experimental Methods in Adsorption and Chromatography), Kiselev, A. and Dreving, V.P., Eds., Moscow: Mosk. Gos. Univ., 1973.
Vargaftik, N.B., Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei (Handbook on Gas and Liquid Thermophysical Properties), Moscow: Nauka, 1972.
Shkolin, A.V., Fomkin, A.A., Pulin, A.L., and Yakovlev, V.Yu., Instruments and Experimental Techniques, 2008, vol. 51, no. 1, p. 150.
Shkolin, A.V. and Fomkin, A.A., Measurement Techniques, 2018, vol. 61, no. 4, p. 395.
Shkolin, A.V., Fomkin, A.A., Men’shchikov, I.E., Pulin, A.L., and Yakovlev, V.Yu., Colloid J. 2019, vol. 81, no. 5, p. 613.
Men’shchikov, I.E., Shkolin, A.V., and Fomkin, A.A., Measurement Techniques, 2018, vol. 61, no. 4, p. 395.
Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Principles of Adsorption Technique), Moscow: Khimiya, 1976.
Barrera, G.D., Bruno, J.A.O., Barron, T.H.K., and Allan, N.L., J. Phys.: Condens. Matter, 2005, vol. 17, p. R217.
Dubbeldam, D., Walton, K.S., Ellis, D.E., and Snurr, R.Q., Angew. Chem., Int. Ed. Engl., 2007, vol. 46, p. 4496.
Peterson, V.K., Kearley, G.J., Wu, Y., Ramirez-Cuesta, A.J., Kemner, E., and Kepert, C.J., Angew. Chem., Int. Ed. Engl., 2010, vol. 49, p. 585.
Novikova, S.I., Teplovoe rasshirenie tverdykh tel (Thermal Expansion of Solids), Moscow: Nauka, 1974.
Dubinin, M.M., Uglerodnye adsorbenty i ikh primenenie v promyshlennosti (Carbon Adsorbents and Their Industrial Application), Plachenov, T.G., Ed., Moscow: Nauka, 1983.
Lakhanpal, M.L. and Flood, E.A., Can. J. Chem., 1957, vol. 35, p. 887.
ACKNOWLEDGMENTS
We are grateful to the Center for Collective Use of the Frumkin Institute of Physical Chemistry and Electrochemistry for allowing us to use experimental equipment.
Funding
This work was supported by the Ministry of Science and Higher Education of the Russian Federation, subject no. 01 201 353 185.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Additional information
Translated by L. Tkachenko
Rights and permissions
About this article
Cite this article
Shkolin, A.V., Fomkin, A.A., Men’shchikov, I.E. et al. Adsorption-Induced and Thermal Deformation of Microporous Carbon Adsorbent upon n-Octane Adsorption. Colloid J 81, 797–803 (2019). https://doi.org/10.1134/S1061933X19060188
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061933X19060188