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Solubilization of Magnesium Octa[(4′-Benzo-15-Crown-5)Oxy]Phthalocyaninate in Aqueous Micellar Solutions of Hexadecyltriphenylphosphonium Bromide

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Abstract

Electronic absorption spectroscopy and fluorimetry have been employed to study the behavior of magnesium octa[(4′-benzo-15-crown-5)oxy]phthalocyaninate (Mg[(B15C5O)8Pc]) in aqueous micellar solutions of sodium dodecyl sulfate and hexadecyltriphenylphosphonium bromide. Conditions have been found for the existence of monomeric Mg[(B15C5O)8Pc] complex in surfactant solutions to provide the possibility of using mixed solutions of the complex and cationic surfactants (alkyltriphenylphosphonium bromides) for photodynamic therapy. In surfactant solutions with different concentrations of micelles (cm) and the complex (cp), the maximum amount of monomeric Mg[(B15C5O)8Pc] is achieved at cm/cp ≥ 4.

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References

  1. Gol’dshleger, N.F., Baulin, V.E., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2014, vol. 50, p. 117.

    Google Scholar 

  2. Lang, K., Kubat, P., Mosinger, J., and Wagnerova, D.M., J. Photochem. Photobiol., A, 1998, vol. 119, p. 47.

    Article  CAS  Google Scholar 

  3. Dumoulin, F., Dusmus, M., Ahsen, V., and Nyokong, T., Coord. Chem. Rev., 2010, vol. 254, p. 2792.

    Article  CAS  Google Scholar 

  4. Gol’dshleger, N.F., Kalashnikova, I.P., Baulin, V.E., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2011, vol. 47, p. 392.

    Google Scholar 

  5. Gol’dshleger, N.F., Chernyak, A.V, Kalashnikova, I.P., Baulin, V.E., and Tsivadze, A.Yu., Zh. Org. Khim., 2012, vol. 82, p. 856.

    Google Scholar 

  6. Ovsyannikova, E.V., Kalashnikova, I.P., Baulin, V.E., Tsivadze, A.Yu., and Alpatova, N.M., Zh. Org. Khim., 2012, vol. 82, p. 1893.

    Google Scholar 

  7. Gol’dshleger, N.F., Lobach, A.S., Gak, V.Yu., Kalashnikova, I.P., Baulin, V.E., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2014, vol. 50, p. 496.

    Google Scholar 

  8. Chen, X., Lan, W., and Huang, J., Chem. Asian J., 2013, vol. 8, p. 3063.

    Article  CAS  PubMed  Google Scholar 

  9. Bıyıklıoglu, Z., Çakır, V., Çakır, D., and Kantekin, H., J. Organomet. Chem., 2014, vol. 749, p. 18.

    Article  CAS  Google Scholar 

  10. Tsivadze, A.Yu., Usp. Khim., 2004, vol. 73, p. 6.

    Google Scholar 

  11. Baulin, V.E., Ovsyannikova, E.V., Kalashnikova, I.P., Girina, G.P., Andreev, V.N., Alpatova, N.M., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2013, vol. 49, p. 7.

    Google Scholar 

  12. Gol’dshleger, N.F., Lobach, A.S., Baulin, V.E., and Tsivadze, A.Yu., Usp. Khim., 2017, vol. 86, p. 269.

    Article  Google Scholar 

  13. Wöhrle, D., Schnurpfeil, G., Makarov, S.G., Kazarin, A., and Suvorova, O.N., Macroheterocycles, 2012, vol. 5, p. 191.

    Article  CAS  Google Scholar 

  14. Gorbunova, Y.G., Martynov, A.G., and Tsivadze, A.Y., in Handbook of Porphyrin Science, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., Singapore: World Scientific, 2012, vol. 25, p. 271.

    Article  Google Scholar 

  15. Martynov, A.G., Gorbunova, Y.G., and Tsivadze, A.Y., Russ. J. Inorg. Chem., 2014, vol. 59, p. 1635.

    Article  CAS  Google Scholar 

  16. Gorbunova, Yu.G., Grishina, A.D., Martynov, A.G., Krivenko, T.V., Isakova, A.A., Savelyev, V.V., Nefedov, S.E., Abkhalimov, E.V., Vannikov, A.V., and Tsivadze, A.Yu., J. Mater. Chem. C, 2015, vol. 3, p. 6692.

    Article  CAS  Google Scholar 

  17. Gorbunova, Yu.G., Enakieva, Yu.Yu., Sakharov, S.G., and Tsivadze, A.Yu., J. Porphyrins Phthalocyanines, 2003, vol. 7, p. 795.

    Article  CAS  Google Scholar 

  18. Selektor, S.L., Shokurov, A.V., Arslanov, V.V., Gorbunova, Y.G., Birin, K.P., Raitman, O.A., Morote, F., Cohen-Bouhacina, T., Grauby-Heywang, Ch., and Tsivadze, A.Yu., J. Phys. Chem. C, 2014, vol. 118, p. 4250.

    Article  CAS  Google Scholar 

  19. Safonova, E.A., Martynov, A.G., Zolotarevskii, V.I., Nefedov, S.E., Gorbunova, Yu.G., and Tsivadze, A.Yu., Dalton Trans., 2015, vol. 44, p. 1366.

    Article  CAS  Google Scholar 

  20. Vannikov, A.V., Gorbunova, Yu.G., Grishina, A.D., and Tsivadze, A.Yu., Fizikokhim. Poverkh. Zashch. Mater., 2013, vol. 49, p. 62.

    Google Scholar 

  21. Nefedova, I.V., Martynov, A.G., Averin, A.A., Kirakosyan, G.A., Tsivadze, A.Yu., and Gorbunova, Yu.G., Isr. J. Chem., 2016, vol. 56, p. 181.

    CAS  Google Scholar 

  22. Safonova, E.A., Martynov, A.G., Nefedov, S.E., Kirakosyan, G.A., Gorbunova, Yu.G., and Tsivadze, A.Yu., Inorg. Chem., 2016, vol. 55, p. 2450.

    CAS  Google Scholar 

  23. Polovkova, M.A., Martynov, A.G., Birin, K.P., Nefedov, S.E., Gorbunova, Yu.G., and Tsivadze, A.Yu., Inorg. Chem., 2016, vol. 55, p. 9258.

    CAS  Google Scholar 

  24. Oluwole, D.O., Yagodin, A.V., Mhkize, N.C., Sekhosana, K.E., Martynov, A.G., Gorbunova, Y.G., Tsivadze, A.Yu., and Nyokong, T., Chem.-Eur. J., 2017, vol. 23, p. 2820.

    Article  CAS  PubMed  Google Scholar 

  25. Orlova, O.V., Sidullina, S.A., and Egorova, S.N., Fundam. Issled., 2013, nos. 5–1, p. 115.

    Google Scholar 

  26. Zakharova, L.R. and Konovalov, A.I., Colloid J., 2012, vol. 74, p. 194.

    Article  CAS  Google Scholar 

  27. Movchan, T.G., Plotnikova, E.V., and Us’yarov, O.G., Colloid J., 2013, vol. 75, p. 319.

    Article  CAS  Google Scholar 

  28. Rusanov, A.I., Mitselloobrazovanie v rastvorakh poverkhnostno-aktivnykh veshchestv (Micellization in Surfactant Solutions), St. Petersburg: Khimiya, 1992.

    Google Scholar 

  29. Rusanov, A.I., Colloid J., 2016, vol. 78, p. 371.

    Article  CAS  Google Scholar 

  30. Movchan, T.G., Rusanov, A.I., and Plotnikova, E.V., Colloid J., 2016, vol. 78, p. 785.

    Article  CAS  Google Scholar 

  31. Vagapova, G.I., Valeeva, F.G., Ibragimova, A.R., Gainanova, G.A., Zakharova, L.Ya., Sikaev, V.V, Galkina, I.V., Tudrii, E.V., and Romanov, A.O., Abstracts of Papers, X1V Molodezhnaya konf. po organicheskoi khimii (14 Young Scientist Conf. on Organic Chemistry), 2011, Yekaterinburg, p. 54.

    Google Scholar 

  32. Shagiddulina, R.A., Zakharova, L.R., Valeeva, F.G., and Kudryavtseva, L.A., Izv. Akad. Nauk, Ser. Khim., 2001, no. 7, p. 1125.

    Google Scholar 

  33. Thakkar, K., Bharatiya, B., Shah, D.O., Ray, D., Aswal, V.A., and Bahadur, P., Colloids Surf. A, 2015, vol. 484, p. 547.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    T. G. Movchan, A. A. Averin, D. V. Baulin, E. V. Plotnikova, V. E. Baulin & A. Yu. Tsivadze

  2. Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. E. Baulin

Authors
  1. T. G. Movchan
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  2. A. A. Averin
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  3. D. V. Baulin
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  4. E. V. Plotnikova
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  5. V. E. Baulin
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  6. A. Yu. Tsivadze
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Correspondence to T. G. Movchan.

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Original Russian Text © T.G. Movchan, A.A. Averin, D.V. Baulin, E.V. Plotnikova, V.E. Baulin, A.Yu. Tsivadze, 2018, published in Kolloidnyi Zhurnal, 2018, Vol. 80, No. 5, pp. 528–540.

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Movchan, T.G., Averin, A.A., Baulin, D.V. et al. Solubilization of Magnesium Octa[(4′-Benzo-15-Crown-5)Oxy]Phthalocyaninate in Aqueous Micellar Solutions of Hexadecyltriphenylphosphonium Bromide. Colloid J 80, 501–512 (2018). https://doi.org/10.1134/S1061933X18050095

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  • DOI: https://doi.org/10.1134/S1061933X18050095

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