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Aqueous solutions of hydroxypropyl cellulose, Tween 80 and their binary mixtures: Colloid-chemical aspects

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Abstract

Tensiometry, dynamic light scattering, and rheology have been used to study the colloid-chemical properties of hydroxypropyl cellulose, Tween 80, and binary mixtures thereof in an aqueous medium and at water/decane and water/air interfaces. The efficiency of a reduction in the interfacial energy under dynamic and static conditions, the surface activity of the components, capability of self-organization in bulk and at interfaces, as well as emulsifying efficiency of the systems, have been analyzed. It has been found that, in a narrow concentration range and at a certain ratio of the components, they exhibit a synergetic effect with respect to a reduction in the interfacial energy, with this effect being due to the formation of a Tween 80–polymer bilayer via hydrogen bonding between hydroxyl groups of hydroxypropyl cellulose and ethoxy units of Tween 80.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    M. V. Poteshnova & N. M. Zadymova

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  1. M. V. Poteshnova
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  2. N. M. Zadymova
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Correspondence to M. V. Poteshnova.

Additional information

Original Russian Text © M.V. Poteshnova, N.M. Zadymova, 2017, published in Kolloidnyi Zhurnal, 2017, Vol. 79, No. 6, pp. 766–777.

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Poteshnova, M.V., Zadymova, N.M. Aqueous solutions of hydroxypropyl cellulose, Tween 80 and their binary mixtures: Colloid-chemical aspects. Colloid J 79, 797–808 (2017). https://doi.org/10.1134/S1061933X17060126

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  • DOI: https://doi.org/10.1134/S1061933X17060126

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